Note that our data is ABSORBANCE versus time, not CONCENTRATION versus time. Absorbance and concentration are proportional according to Beer's law A = abc or A = ElC so the data is still useful. However, extracting the rate constant from a linear plot may be annoying if the rate constant is supposed to incorporate units of concentration. For example, if the rate constant should be 0.25/s then there is no problem, but if the rate constant should be 0.25 M/s then how can we get the molar unit directly from a graph involving ABSORBANCE and time? We can't. We'd need to involve Beer's law. Hopefully we won't need to do that. Identify the symbols used in Beer's law. A molar absorbtivity/ extinction coefficient a molar concentration b absorbance path length through the sample с
Note that our data is ABSORBANCE versus time, not CONCENTRATION versus time. Absorbance and concentration are proportional according to Beer's law A = abc or A = ElC so the data is still useful. However, extracting the rate constant from a linear plot may be annoying if the rate constant is supposed to incorporate units of concentration. For example, if the rate constant should be 0.25/s then there is no problem, but if the rate constant should be 0.25 M/s then how can we get the molar unit directly from a graph involving ABSORBANCE and time? We can't. We'd need to involve Beer's law. Hopefully we won't need to do that. Identify the symbols used in Beer's law. A molar absorbtivity/ extinction coefficient a molar concentration b absorbance path length through the sample с
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question

Transcribed Image Text:Note that our data is ABSORBANCE versus time, not CONCENTRATION versus time. Absorbance and concentration are proportional according to Beer's law A = abc or
A = ElC so the data is still useful. However, extracting the rate constant from a linear plot may be annoying if the rate constant is supposed to incorporate units of
concentration. For example, if the rate constant should be 0.25/s then there is no problem, but if the rate constant should be 0.25 M/s then how can we get the molar unit
directly from a graph involving ABSORBANCE and time? We can't. We'd need to involve Beer's law. Hopefully we won't need to do that.
Identify the symbols used in Beer's law.
A
molar absorbtivity / extinction coefficient
a
molar concentration
b
absorbance
path length through the sample
C
Expert Solution

This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
Step by step
Solved in 2 steps with 2 images

Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning

Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education

Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning

Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY