Macmillan Learning cis-A9-hexadecenoate Fatty acids are carboxylic acids with long hydrophobic tails. Draw the line-bond structure of cis-A9-hexadecenoate. Clearly show the cis-trans stereochemistry. о H
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- Cyclopentanecarboxylic acid and 4-hydroxycyclohexanone have the same formula (C6H10O2), and both contain an —OH and a C=O group. How could you distinguish between them using IR spectroscopy?16-17 Propylamine (bp 48°C), ethylmethylamine (bp 37°C), and trimethylamine (bp 3°C) are constitutional isomers with the molecular formula C3HgN. Account for the fact that trimethylamine has the lowest boiling point of the three and propylamine has the highest.Arrange the following compounds in decreasing order of acidity * |- CICH2CH2CH2COOH Il - CH3CH2CHCICOOH III – CH3CHCICH2COOH III > I> || O I > II > || O I > I| > II III > || >|
- 16) SN1 S-2-bromohexane C,H;OH + ?Ketones typically have a pka of approximately 20. While this is certainly not a strong acid it is much stronger than a typical alkane sp3-CH. using acetone as an example, explain why ketones are much more acidic than Alkanes.PQ-12. What is the major product of this reaction? Н (В) ОН 1) LiAIH4, Et2O 2) H30+ (D) ОН
- DRAW STRUCTURE V2- 150BU+YL -G6-diMEtHYL HE PAANOIC ACID » (55 72)-4-150PROPYNONA-5,7-DIE NOIC ACIO 3) 3-CY CIobutyL~4-CY CIO He xY LBEN Z0iC ACIDleft 4. Consider the following equilibrium: 29925610 + Aga weak and Sung base Bast CORS + 1ght base: Strong ad d AddOH ress stable OH Is the carboxylate anion (CH3CH₂COO) an appropriate base to deprotonate the alcohol? A) yes, because the equilibrium favors the left side B) yes, because the equilibrium favors the right side C) no, because the equilibrium favors the left side D) no, because the equilibrium favors the right side OH COO bas9. NAHSO3 CH3 - C- CH3 19)_ 10. _(10a) NaOH → HC-O-Na + _(10b)_
- An organic acid can be represented by: ‖ CH3 – CH2 – C – H O ‖ CH3 – CH2 – C – OH O ‖ CH3 – C – CH3 CH3 – CH2 - O – CH3HCN HPO4 2- CN-1 + HPO4-1 Which specie is bronsted base?Explain why phenol (C6H50H) is substantially more acidic than methanol (CH3OH), but benzoic acid (C6H5CO2H) is not much more acidic than acetic acid (CH3CO2H). Нас — ОН ОН H3C- ОН OH pKa = 15.5 pKa = 10.0 pk = 4.75 pk = 4.2