In the following problems, design a realistic method for the synthesis of 2 products in the reaction from the specified starting (reactant) molecule. Assume that simple inorganic and organic reagents, and suitable solvents, are readily available, but they must be specified. C. OH d. OH
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- 5. Complete textbook problems covered in class by drawing the products to the right of each reaction arrow. Assume the presence of excess acid or base and halogen. [3 pts each] a. Cl2 H2O, HCI b. 12, ΟΗ C. I2, OH d. Br2 CH3CO₂HProvide the missing compounds and reagents in the reaction scheme. Identify reagent 5. OH reagent 2 reagent 1 H2SO4 но Compound 1 (conc.) 1) BH3 2) H,O, H,SO, (conc.) NaOH, H2O reagent 3 CrO3, H* A Compound 4 NABH4 1) O3 2) Zn, H;O* reagent 5 reagent 4 H,SO4 Compound 3 Compound 2 1) CH;MgBr (conc.) 2) H;O+ Identify reagent 1. Identify reagent 2. Identify reagent 3. Identify reagent 4. 1) CH3MGB1 2) H;O* H,SO̟ (conc.) H,SO, (conc.) H,SO, (conc.) CrO3, H+ 1) ВН, NaBH4 1) O3 NaBH, 2) H2O2 2) Zn, H3O* 1) CH,MgBr 1) BH3 NaBH, 2) H3O+ NABH, 2) H,O2 1) CH;MgBr 1) O3 1) BH3 1) O3 2) Zn, H3O* 2) H;0* 2) Zn, H,O+ 2) H,O2 1) O3 CrO3, H+ CrO3, H+ H,SO4 (conc.) 2) Zn, H,O* 1) CH; MgBr 2) H,0* 1) ВН, CrO3, H* 2) H,O,6. Provide reagents and intermediates in the indicated boxes to complete the reaction scheme. + H NaBH3CN, HCI (two steps, no acidic hydrolysis, from one product) 016H (w/o heat) 1. MeLi (xs) 2. HCI, H₂O NH₂ 1. Saponification 2. A 0 1. MeMgBr (xs) 2. HCI, H₂O 018 Me NH₂ 1. Dibal H, 2. H3O+ POCk3, pyr or + 1. LIAIH(O'Bu)3 (XS) 2. acidic workup
- Complete the following reactions by providing missing reagents or products: i. ii. iii. OH i. ii. H3O+ OEt i. CH3MgCl ii. H3O+ MgCl MgBr i. Xo ii. H3O+ i. NaBH4 ii. H3O+ OHVI. Complete the following multistep synthesis problems starting from given starting material and any reagent containing no more than four carbon atoms. Reaction mechanisms are not required.. 82 A. B. NH₂ -> î NH₂ NH₂Choose among the choices (an) example/s of (an) solvents that do not undergo autoprotolysis. A. H2O B. CH3CH2OH C. CH3CN D. Both A and B E. All of the above