13Draw the complete arrow pushing mechanism for thefollowing reaction. Indicate the Lewis acid and Lewis base(LA or LB) and whether they are also Bronsted acids andbases (BA or BB) for each intermolecular reaction. Addnonbonding electrons as necessary. Draw all the importantresonance structure of the intermediates. You can useabreviated +H+/-H* notation.To preview image Click HereNH3NHTSOH (cat.)

References Smith, M. B. (2020). March's advanced organic chemistry: reactions, mechanisms, and…

Answered: 13 Draw the complete arrow pushing…

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter20: Acidity And Pka Of Phenols

Section: Chapter Questions

Problem 11E

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Draw the step-by-step curved-arrow pushing mechanism of the following reaction. All lone pair electrons must be included in your drawing. Ph conc. HBr heat Problem viewing the exam, Click Preview Here CH3Br + Br Ph
Please show the reaction that does occur, with both products and determine which way the equilibrium of the reaction lies and why?
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Use the following reaction and information to answer a and b. 2ClO2(aq)+2OH-(aq)-->ClO-(aq)+Cl2-(aq)+H2O(l) [ClO2](M) [OH-](M) Initial rate (M/s) 0.060 0.030 0.0248 0.020 0.030 0.00276 0.020 0.090 0.00828 a. What is the order of this reaction in respect to ClO2, with respect to OH-, and the overall order? Assume the rate law has the form rate=k[ClO2]a[OH-]b b. What is the value of the rate constant? Include the units and why the unit make sense.
To preview image click here Give a curved arrow pushing mechanism for the following reaction, indicate the Lewis and Bronsted acids/bases for each intermolecular step, include all important resonnace contributors for intermediates, give the number of steps in your mechanism, indicate the Lewis and Bronsted acids/bases for each Intermolecular step, show where every proton comes from and goes to (no +H+/-H+), add H atoms and non-bonding electrons as necessary. H NaOH/EtOH H heat
Which of the following statements is true about the mechanism of acid-base reactions? The transition state has a tetrahedral A-H-B bond angle. The proton is shared only by B in the transition state. During the molecular collision in an acid-base reaction, the trajectory of the base, B-, must be toward the A of A-H. For an acid to transfer its proton to a base, the two entities must collide with specific geometry.
Draw out the full reaction mechanism for this acid- base reaction: Draw the arrows to show how the electrons flow from source to sink. H H | | H-C-C- Br: H H : I H C-N. H H H

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