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- By using only amide/Peptide bond forming rxn and a lkylation rxns. Provide all the reaction steps with the reagent needed and conditions with out showing the mechanism for each step to form the product. Note: Use protecting groups like (Boc, Fmoc, and others) H¸NNH rxns. By using only amide / Peptide bond forming rxn and alkylation Provide all the reaction steps with the reagent needed and conditions showing the mechanism for each step to form the product. protecting groups. like (Boc, Fmoc, and others) with out Note: Use HN H₂N. -NH₂- + ΝΗ29. The major product in the following reaction sequence is (i) mCPBA, NaHCO3 (ii) NaOH, H2O MeO (iii) I2, KI, NAHCO3, H20please answer in words.
- Provide the mechanism for the reacrion below.Please answer all parts:2. Each of 10 stereoisomeric sugar derivatives can be prepared via a multiple-step synthesis starting from either glucuronolactone 1D or its enantiomer 1L. (J. Org. Chem. 2012, 77, 7777-7792). 1L A. Draw the structure of 1L. 1D OH HO N OH HO OH sugar derivative B. How many stereoisomers of 1D are possible? C. Now consider the 10 stereoisomeric sugar derivatives. Draw the structures of the eight chiral products (as pairs of enantiomers) and the two achiral products (hint: meso).
- * Your answer is incorrect. Which synthetic route(s) would complete the reaction shown? Br ? 1 SO II O III O I and II Oland III OH + enantiomer HO Synthesis I: 1. NaCCCH3; 2. Na/NH3(1):3. OsO4; 4. NaHSO₂, H₂O Synthesis II: 2. NaCCCH3: 2. H₂, Lindlar's catalyst; 3. MCPBA: 4. aq. H₂SO4 Synthesis III: 1. NaCCCH3: 2. H₂, Pt: 3. MCPBA: 4. aq. H₂SO48. Draw the mechanism and product for the following reactions. (20 pts.) a. b. C. d. НОВИ H NaOCH2 половая CHO ZI CH3 1. Excess CHI, NaOH 2. Ag2O, Heat HO OH HOM HO CH3CH2NH2 H2SO4, H2O (pH 4.5) (CH3CH2)2NH H2SO4, H₂O (pH 4.5) mainedooM noilons A mains ooM mainedboMKk.319.