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- (d) HO MOH Laurediol Br+ Bromoperoxidase Br ..OH Prelaureatin(a) Draw a mechanism using the curved arrow-formalism for the O-4 methylation of thymine. Is thenucleophilic substitution in the first step an SN1 or SN2 reaction? Explain.By using only amide/Peptide bond forming rxn and a lkylation rxns. Provide all the reaction steps with the reagent needed and conditions with out showing the mechanism for each step to form the product. Note: Use protecting groups like (Boc, Fmoc, and others) H¸NNH rxns. By using only amide / Peptide bond forming rxn and alkylation Provide all the reaction steps with the reagent needed and conditions showing the mechanism for each step to form the product. protecting groups. like (Boc, Fmoc, and others) with out Note: Use HN H₂N. -NH₂- + ΝΗ
- please answer in words.2. Each of 10 stereoisomeric sugar derivatives can be prepared via a multiple-step synthesis starting from either glucuronolactone 1D or its enantiomer 1L. (J. Org. Chem. 2012, 77, 7777-7792). 1L A. Draw the structure of 1L. 1D OH HO N OH HO OH sugar derivative B. How many stereoisomers of 1D are possible? C. Now consider the 10 stereoisomeric sugar derivatives. Draw the structures of the eight chiral products (as pairs of enantiomers) and the two achiral products (hint: meso).* Your answer is incorrect. Which synthetic route(s) would complete the reaction shown? Br ? 1 SO II O III O I and II Oland III OH + enantiomer HO Synthesis I: 1. NaCCCH3; 2. Na/NH3(1):3. OsO4; 4. NaHSO₂, H₂O Synthesis II: 2. NaCCCH3: 2. H₂, Lindlar's catalyst; 3. MCPBA: 4. aq. H₂SO4 Synthesis III: 1. NaCCCH3: 2. H₂, Pt: 3. MCPBA: 4. aq. H₂SO4
- Draw the mechanism of the hydration and the enol ketone tautomerization reaction using one of the alkynes in calicheamicin. Use the formal arrow pushing formalism and show the product of this hydration.Account for the rapid rate of methanolysis of ClCH2OCH2CH3 even though the substrate is a primary halide. Hint: The reaction of the substrate with ethanol proceeds by SN1 mechanism. Draw the Lewisstructures.By using only amide/Peptide bond forming rxn and a lKylation rxns. Provide all the reaction steps with the reagent needed and conditions with out showing the mechanism for each step to form the product. Note: Use protecting groups like (Boc, Fmoc, and others) H2NNH2+