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- (d) HO MOH Laurediol Br+ Bromoperoxidase Br ..OH PrelaureatinPlease provide mechansim. THF quetiapine 0.779-O-TBS CC(C)(C)[SI](C)(C)OCCOCCN1. HCI HCIWhich of the following bases are strong enough to deprotonate CH3CH2CH2C≡CH (pKa = 25) so that equilibrium favors the products: (a) H2O; (b) NaOH; (c) NaNH2; (d) NH3; (e) NaH; (f) CH3Li?
- When aspirin is made from acetic acid, the by product is H2O; when acetic anhydride 1Sused, the by-product is acetic acid. When acetyl chloride is used (see above), the by product is HC1. Which route should you use if you were working for Leica, a company that mass produces aspirin on a daily basis? Why?The C2-epimer of D-xylose is called (blank 1). The enediol rearrangementconverts an aldose into a (blank 2). The aldopentose embedded in RNA is(blank 3). An aldopentose would have (blank 4) possible stereoisomers,of whichBlankwould be D-sugars. An ketopentose would have (blank 4) possiblestereoisomers, of which (blank 5) would be D-sugarsa) Propose a synthesis using a maximum number of 5 synthetic steps, for the dipeptide NH2-ILE-ASP-COOH. Explain your choice of protecting groups
- Kk.277.Account for the rapid rate of methanolysis of ClCH2OCH2CH3 even though the substrate is a primary halide. Hint: The reaction of the substrate with ethanol proceeds by SN1 mechanism. Draw the Lewisstructures.3a. 3b. 3c 3d. 3e. CO₂ clavulanic acid CH₂-OH H Answer the following questions about clavulanic acid. Does clavulanic acid inhibit D-alanyl-D-alanine transpeptidase? Does clavulanic acid contain a ß-lactam? Does clavulanic acid contain a thiazolium ring? What is the result of the treatment of penicillinase with clavulanic acid? Does clavulanic acid form a covalent acyl-enzyme intermediate with penicillinase?
- (a) For each structure, identify all of the possible hydrogen bond donors (HBDS) and hydrogen bond acceptors (HBAS). Remember, some functional groups may be able to act as HBDS and HBAS. HO MeO Capsaicin Citalopram HO HO HO HO- Prostaglandin D2 Atropine (b) Eukaryotic cell membranes function as a hydrophobic barrier around the cell and prevent the passage of polar or charged molecules. Briefly explain how cell membranes work and use a simple diagram to aid your explanation. Refer specifically to hydrophobic and hydrophilic components in their structure.Shown here is a/anglycosidic linkage. CH₂OH CH₂OH I OH Н OH Н O Alpha Beta OL- O D- О Н I ОН HO OH -О Н Н H OH OH5. Glycolysis is a metabolic pathway that converts glucose into pyruvate while synthesizing high-energy molecules. During one step of Glycolysis, glucose-6 phosphate (an aldose) is converted to fructose-6-phosphate (a ketose) via an ene-diol intermediate. Draw arrow pushing mechanism to describe this isomerization. Use B: and HA as surrogates for basic/acidic amino acid residues. ОН ОН О OP ОН ОН ОН ОН ОН OP ОН