How does the rate law for the overall reaction match the experimental rate law? Do the elementary steps add up to the overall reaction? Show your work. Is the proposed mechanism valid? Explain why or why not.
How does the rate law for the overall reaction match the experimental rate law? Do the elementary steps add up to the overall reaction? Show your work. Is the proposed mechanism valid? Explain why or why not.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![Problem 2
Consider the following reaction between nitrogen dioxide gas and carbon monoxide
gas
21 + 2H* + H2O2 → I2 + 2H20 (g)
The experimentally determined rate law for this reaction is Rate = k [I"] [H2Oz].
The following mechanism has been proposed
I + H2O2 → HOI + OH"
HOI + I → OH" + I2 (g)
Slow
Fast
H* + OH" → H2O
Fast](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F42c6b712-c6a2-4683-92be-736f944a312b%2Fe1b2e0dd-e174-475f-a760-2f3901a08eee%2Fktv8l8a_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Problem 2
Consider the following reaction between nitrogen dioxide gas and carbon monoxide
gas
21 + 2H* + H2O2 → I2 + 2H20 (g)
The experimentally determined rate law for this reaction is Rate = k [I"] [H2Oz].
The following mechanism has been proposed
I + H2O2 → HOI + OH"
HOI + I → OH" + I2 (g)
Slow
Fast
H* + OH" → H2O
Fast

Transcribed Image Text:How does the rate law for the overall reaction match the experimental rate law?
Do the elementary steps add up to the overall reaction? Show your work.
Is the proposed mechanism valid? Explain why or why not.
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