How does the rate law for the overall reaction match the experimental rate law? Do the elementary steps add up to the overall reaction? Show your work. Is the proposed mechanism valid? Explain why or why not.
How does the rate law for the overall reaction match the experimental rate law? Do the elementary steps add up to the overall reaction? Show your work. Is the proposed mechanism valid? Explain why or why not.
General Chemistry - Standalone book (MindTap Course List)
11th Edition
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Chapter13: Rates Of Reaction
Section: Chapter Questions
Problem 13.140QP: The following data were collected for the reaction A(g)+B(g) Products. a Determine the rate law for...
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Question
![Problem 2
Consider the following reaction between nitrogen dioxide gas and carbon monoxide
gas
21 + 2H* + H2O2 → I2 + 2H20 (g)
The experimentally determined rate law for this reaction is Rate = k [I"] [H2Oz].
The following mechanism has been proposed
I + H2O2 → HOI + OH"
HOI + I → OH" + I2 (g)
Slow
Fast
H* + OH" → H2O
Fast](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F42c6b712-c6a2-4683-92be-736f944a312b%2Fe1b2e0dd-e174-475f-a760-2f3901a08eee%2Fktv8l8a_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Problem 2
Consider the following reaction between nitrogen dioxide gas and carbon monoxide
gas
21 + 2H* + H2O2 → I2 + 2H20 (g)
The experimentally determined rate law for this reaction is Rate = k [I"] [H2Oz].
The following mechanism has been proposed
I + H2O2 → HOI + OH"
HOI + I → OH" + I2 (g)
Slow
Fast
H* + OH" → H2O
Fast
![How does the rate law for the overall reaction match the experimental rate law?
Do the elementary steps add up to the overall reaction? Show your work.
Is the proposed mechanism valid? Explain why or why not.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F42c6b712-c6a2-4683-92be-736f944a312b%2Fe1b2e0dd-e174-475f-a760-2f3901a08eee%2F6biockn_processed.jpeg&w=3840&q=75)
Transcribed Image Text:How does the rate law for the overall reaction match the experimental rate law?
Do the elementary steps add up to the overall reaction? Show your work.
Is the proposed mechanism valid? Explain why or why not.
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