Part 1 Element D reacts with F2 to form gaseous DF4. A series of experimental trials to determine the rate law expression for the reaction. 1. A student claims that the reaction is second order with respect to F2 (g). Do you agree or disagree? Justify your answer. 2. If Element D is in group 16, then the molecular geometry of DF4 (g) is see-saw. Do you agree or disagree with this claim? Justify your answer in terms of VSEPR theory.
Part 1
Element D reacts with F2 to form gaseous DF4. A series of experimental trials to determine the rate law expression for the reaction.
1. A student claims that the reaction is second order with respect to F2 (g). Do you agree or disagree? Justify your answer.
2. If Element D is in group 16, then the molecular geometry of DF4 (g) is see-saw. Do you agree or disagree with this claim? Justify your answer in terms of VSEPR theory.
Part 2
The particle model below shows the moles of D (g) and F2 (g) present after a separate reaction occurs. Assume each particle represents one mole. Note, the “Before Reaction” box is intentionally left blank.
1. What is the partial pressure of D (g) if the final total pressure is 12 atm?
2. Assuming that only D and F2 are present before the reaction, how many moles of D and F2 that initially were present?
![D (g) + 2 F2 (g) → DF, (g)
Trial
Initial Pp (torr)
Initial PF2 (torr)
Initial Rate of Appearance of DF, (g) (torr/min)
1
3000
3000
2.50x102
2
6000
3000
5.00x102
3
3000
6000
10.0x102](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fdba83b6b-579b-4206-8eb0-b091f3e3abf6%2Fb5af4ef9-7101-4f57-ad73-77a8abc4641b%2Fglt9c6q_processed.jpeg&w=3840&q=75)
![O = D
= F2
00
= DF.
Before Reaction
After Reaction](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fdba83b6b-579b-4206-8eb0-b091f3e3abf6%2Fb5af4ef9-7101-4f57-ad73-77a8abc4641b%2Faftgfel_processed.jpeg&w=3840&q=75)
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