4. Consider the following 3 step reaction mechanism: Step 1 H₂ 2H fast Step 2 Step 3 H + HCO H + CO a. What is the overall reaction? HCO slow H₂CO fast b. Identify the intermediates in the reaction mechanism. c. Write a rate law expression for each step of the mechanism including any reversible reactions. c. What is the predicted rate law expression? Be sure to only list reactants from the overall equation and not intermediates in the rate law expression.
4. Consider the following 3 step reaction mechanism: Step 1 H₂ 2H fast Step 2 Step 3 H + HCO H + CO a. What is the overall reaction? HCO slow H₂CO fast b. Identify the intermediates in the reaction mechanism. c. Write a rate law expression for each step of the mechanism including any reversible reactions. c. What is the predicted rate law expression? Be sure to only list reactants from the overall equation and not intermediates in the rate law expression.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**4. Consider the following 3-step reaction mechanism:**
**Step 1:**
\[ \text{H}_2 \rightleftharpoons 2\text{H} \quad \text{(fast)} \]
**Step 2:**
\[ \text{H} + \text{CO} \rightarrow \text{HCO} \quad \text{(slow)} \]
**Step 3:**
\[ \text{H} + \text{HCO} \rightarrow \text{H}_2\text{CO} \quad \text{(fast)} \]
---
**a. What is the overall reaction?**
---
**b. Identify the intermediates in the reaction mechanism.**
---
**c. Write a rate law expression for each step of the mechanism including any reversible reactions.**
---
**d. What is the predicted rate law expression?**
*Be sure to only list reactants from the overall equation and not intermediates in the rate law expression.*
---
In this mechanism, intermediates are substances formed in one step of the reaction and consumed in another. The rate law expressions depend on the slow step and the concentration of the substances involved. The overall reaction combines all steps, cancelling out intermediates.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F5b8356a3-8ffd-4b0d-99e3-2fe5523dae0d%2F4671c017-d560-4837-a7b2-9dd7f65d9177%2Ffx1jfz5_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**4. Consider the following 3-step reaction mechanism:**
**Step 1:**
\[ \text{H}_2 \rightleftharpoons 2\text{H} \quad \text{(fast)} \]
**Step 2:**
\[ \text{H} + \text{CO} \rightarrow \text{HCO} \quad \text{(slow)} \]
**Step 3:**
\[ \text{H} + \text{HCO} \rightarrow \text{H}_2\text{CO} \quad \text{(fast)} \]
---
**a. What is the overall reaction?**
---
**b. Identify the intermediates in the reaction mechanism.**
---
**c. Write a rate law expression for each step of the mechanism including any reversible reactions.**
---
**d. What is the predicted rate law expression?**
*Be sure to only list reactants from the overall equation and not intermediates in the rate law expression.*
---
In this mechanism, intermediates are substances formed in one step of the reaction and consumed in another. The rate law expressions depend on the slow step and the concentration of the substances involved. The overall reaction combines all steps, cancelling out intermediates.
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