Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question

Transcribed Image Text:2. Consider this two step mechanism for a reaction...
Step 1 NO₂ + 03
NO3 + 0₂
Step 2
NO3 + NO₂
a. What is the overall reaction?
→ N₂O5
slow; rate determining step
fast
b. Identify the intermediates in the mechanism.
c. Write the rate law expression for each step of the mechanism including any reversible
reactions.
c. What is the predicted rate law expression? Be sure to only list reactants from the
overall equation and not intermediates in the rate law expression.
Expert Solution

Step 1
Given
slow;
- NO2 + 02 ---->NO3 + 03
fast
NO3 + NO2 ----> N2O5
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