) hoom temp Key 2982 M & = permittivity free space 8.854× 10-12 F/M Ionic strength (I) = 1.00 x 10-5 mol/ Boltzmann Constant (K) = 1.38× 10-23 m² ks 5²k"" Avogadro # (NA) = 6.022× 1023 Mol Elementary Charge (e) = 1.602 × 10-19 c Permittivity of solvent (εr) = 78.5F/m Calculate Debye length free space ionic Strength Calculate 1.00 × 10 = Mol/L X 1,000/m-3 0.01.1/m3 Ap = √Er Eo KBT 2NA E² I Plug value in equation 78.5F/m x 8.85 X 10-12 x 1.38 × 10-23 X 298k 2 x 6.022 × 10-23 mo Numerator 78.5 x 8.854×10 Denominator 2 x 6.022 x 10 π x (1.602 × 10 - 19 (c) 2x1.00×105 16H26 971 A -12 = 6.95 X10 -10 -23 -30 ✗ 1.38X10 X 298K = 2.86 x 10 -38 2.57 X10 2 -65 -23 x (1.602 × 10-19) ² x 1.00 × 105 = 3.09_XID -30 2.86X10 = 3.09×10 -65 פו - 1.69 1.76-7 = 9.62×10-14 27
) hoom temp Key 2982 M & = permittivity free space 8.854× 10-12 F/M Ionic strength (I) = 1.00 x 10-5 mol/ Boltzmann Constant (K) = 1.38× 10-23 m² ks 5²k"" Avogadro # (NA) = 6.022× 1023 Mol Elementary Charge (e) = 1.602 × 10-19 c Permittivity of solvent (εr) = 78.5F/m Calculate Debye length free space ionic Strength Calculate 1.00 × 10 = Mol/L X 1,000/m-3 0.01.1/m3 Ap = √Er Eo KBT 2NA E² I Plug value in equation 78.5F/m x 8.85 X 10-12 x 1.38 × 10-23 X 298k 2 x 6.022 × 10-23 mo Numerator 78.5 x 8.854×10 Denominator 2 x 6.022 x 10 π x (1.602 × 10 - 19 (c) 2x1.00×105 16H26 971 A -12 = 6.95 X10 -10 -23 -30 ✗ 1.38X10 X 298K = 2.86 x 10 -38 2.57 X10 2 -65 -23 x (1.602 × 10-19) ² x 1.00 × 105 = 3.09_XID -30 2.86X10 = 3.09×10 -65 פו - 1.69 1.76-7 = 9.62×10-14 27
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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During the lecture, we calculated the Debye length at physiological salt concentrations and temperature, i.e. at an ionic strength of 150 mM (i.e. 0.150 mol/l) and a temperature of T=310 K. We predicted that electrostatic interactions are effectively screened beyond distances of 8.1 Å in solutions with a physiological salt concentration.
What is the Debye length in a sample of distilled water with an ionic strength of 10.0 µM (i.e. 1.00 * 10-5 mol/l)? Assume room temperature, i.e. T= 298 K, and provide your answer as a numerical expression with 3 significant figures in Å (1 Å = 10-10 m).
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