3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction ofTitanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride andhydrogen chloride gas.(a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride(b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then addedto bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of thereaction?(c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?

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Answered: 3. Titanium(III) chloride can be used…

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter20: Chemistry Of Hydrogen, Elements In Group 3a Through 6a, And The Noble Gases

Section: Chapter Questions

Problem 20.46QE

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Metallic titanium and its alloys (especially those with aluminum and vanadium) combine the advantages of high strength and lightweight and are therefore used widely in the aerospace industry for the bodies and engines of airplanes (Figure 2.4). The major natural source for titanium is the ore rutile, which contains titanium dioxide (TiO2).(a) An intermediate in the preparation of elemental titanium from TiO2 is avolatile chloride of titanium (boiling point 136°C) that contains 25.24%titanium by mass. Determine the empirical formula of this compound.(b) At 136°C and atmospheric pressure, the density of this gaseous chloride is 5.6 g L-1 . Under the same conditions, the density of gaseous nitrogen (N2, molar mass 28.0 g mol-1 ) is 0.83 g L-1 . Determine the molecular formula of this compound.(c) The titanium chloride dealt with in parts (a) and (b) is produced by thereaction of chlorine with a hot mixture of titanium dioxide and coke (carbon), with carbon dioxide generated as a…
Thortveitite is a mineral that contains the silicate ion [Si2O7]6-. The structure of this ion is such that the each Si atom is bonded to three terminal oxygen atoms, and the seventh O atom forms a bridge between the two Si atoms:[O3Si-O-SiO3]6-
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(b) Many structures of ionic compounds have been described in terms of close packing of a large anion, X, with a cation, A, occupying tetrahedral or octahedral holes. (1) In a cubic close packed lattice, how many octahedral holes are there per lattice ion? (ii) What is the formula of a compound based upon a cubic close packed lattice in which of the octahedral holes are filled? (ii) State the coordination numbers and geometries of A and X In the crystal lattice in part (b)(ii) above.
Magnesium is obtained by electrolysis of molten MgCl2. (a) Why is an aqueous solution of MgCl2 not used in the electrolysis?
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Phosphorus (P) is present in a germanium (Ge) sample. Assume that one of its five valence electrons revolves in a Bohr orbit around each P+ ion in the Ge lattice. (a) If the effective mass of the electron is 0.17 me and the dielectric constant of Ge is 16, find the radius of the first Bohr orbit of the electron. (b) Ge has a band gap (Eg) of 0.65 eV. How does the ionization energy of the above electron comparing to Eg and kBT at room temperature?
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