3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction ofTitanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride andhydrogen chloride gas.(a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride(b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then addedto bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of thereaction?(c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?

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Answered: 3. Titanium(III) chloride can be used…

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter20: Chemistry Of Hydrogen, Elements In Group 3a Through 6a, And The Noble Gases

Section: Chapter Questions

Problem 20.46QE

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Silicon carbide (SiC) is made by the high-temperature reaction of silica sand (quartz) with coke; the byproduct is carbon monoxide.(a) Write a balanced chemical equation for this reaction.(b) Calculate the standard enthalpy change per mole of SiC produced.(c) Predict (qualitatively) the following physical properties of silicon carbide: conductivity, melting point, and hardness.
Tellurium forms a compound with fluorine in which the tellurium ion has an oxidation number of +4. Write the chemical formula of the compound. Do not include the phase designation in the answer.
Selenium is prepared by the reaction of H₂SeO₃ with gaseous SO₂. (a) What redox process does the sulfur dioxide un-dergo? What is the oxidation state of sulfur in the product? (b) Given that the reaction occurs in acidic aqueous solution,what is the formula of the sulfur-containing species? (c) Write the balanced redox equation for the process
Thortveitite is a mineral that contains the silicate ion [Si2O7]6-. The structure of this ion is such that the each Si atom is bonded to three terminal oxygen atoms, and the seventh O atom forms a bridge between the two Si atoms:[O3Si-O-SiO3]6-
Predict the products of each of the following reactions and then balance the chemical equations.(a) Fe is heated in an atmosphere of steam.(b) NaOH is added to a solution of Fe(NO3)3.(c) FeSO4 is added to an acidic solution of KMnO4.(d) Fe is added to a dilute solution of H2SO4.(e) A solution of Fe(NO3)2 and HNO3 is allowed to stand in air.(f) FeCO3 is added to a solution of HClO4.(g) Fe is heated in air.
(b) Many structures of ionic compounds have been described in terms of close packing of a large anion, X, with a cation, A, occupying tetrahedral or octahedral holes. (1) In a cubic close packed lattice, how many octahedral holes are there per lattice ion? (ii) What is the formula of a compound based upon a cubic close packed lattice in which of the octahedral holes are filled? (ii) State the coordination numbers and geometries of A and X In the crystal lattice in part (b)(ii) above.
Magnesium is obtained by electrolysis of molten MgCl2. (a) Why is an aqueous solution of MgCl2 not used in the electrolysis?
Discuss the nature of bonds in NaCl and diamond. What do you mean by directionality of covalent bonds? Why materials with covalent bonds are brittle?
Phosphorus (P) is present in a germanium (Ge) sample. Assume that one of its five valence electrons revolves in a Bohr orbit around each P+ ion in the Ge lattice. (a) If the effective mass of the electron is 0.17 me and the dielectric constant of Ge is 16, find the radius of the first Bohr orbit of the electron. (b) Ge has a band gap (Eg) of 0.65 eV. How does the ionization energy of the above electron comparing to Eg and kBT at room temperature?
Would the reaction of magnesium, mg with oxygen be more or less vigorous than Al?
Knowing that the reaction yield: FeS2 + O2 → Fe2O3 + SO2 is 75%, from 360 g of iron disulfide, calculate: a) The amount of iron (III) oxide produced. b) The volume of SO2, measured at 0 ºC and 1 atm, that will be obtained.
Silica (SiO2) is an impurity that must be removed from ametal oxide or sulfide ore when the ore is being reduced toelemental metal. To do this, lime (CaO) is added. It reactswith the silica to form a slag of calcium silicate (CaSiO3),which can be separated and removed from the ore.(a) Write the balanced equation for this process.(b) Can this be considered a Lewis acid–base reaction? Ifso, what is the Lewis acid and what is the Lewis base?

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