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Highlight the most acidic hydrogen
draw the conjugate base under each molecule
determine which molecule is the stronger acid. Explain why.
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- CH3 1) Hg(OAc)2 H20 a) 2) NaBH4 H3C CH3 1) BH3 D 2) H,OH,0Identify the following pairs of structures as enantiomers, diastereomers, or identical molecules. Name the chiral centers as R or S. Et Et Br- HO. Но- Br HO HO -Br -Br Et Et OH NH2 HO H. H- CI "Me Me. -OH -NH2 ci Pr Pr H- Ph Ph “NH2 Ph. Н. -NH2 -Ph Pr Pr BrH2C НО Me. но HO, „Me HO Me Me “CH2Br ČHĄBr ČH;Br OH OH Me Me H- H. -CH2CI H- OH СООН ČH2CIAnswer each question and justify your answer by doing ALL of the following: Identify the type of substance and important interpartide force(s) for both substances. Explain how you know (substances and forces). For each molecular substance, fully justify how you know if it is polar or nonpolar. Provide a Lewis structure, a geometry sketch, calculation of AEN| values, and a discussion of symmetry. Identify which of the two substances has stronger interparticle forces. If they have the same type of interparticle force, explain how you know which is stronger. Answer the question by connecting the property asked about to strength of interparticle forces. Use complete sentences, write all words out (no abbreviations) and be specific and complete with all explanations. Do not refer to any actual data.
- K An oil company needs to fill orders for 91-octane gas, but only has 88- and 92-octane gas on hand. The octane rating is the percentage of isooctane in the standard fuel. How many liters of 88-octane gas should be mixed with 300 liters of 92-octane gasoline to get a mixture that is 91-octane gas? Let x be the amount of 88-octane gas used in the mixture. Complete the following chart. Type of Gas 88-octane 92-octane Mixture Quantity X 300 x+300 % Isooctane 88% 92% 91% Amount of Isooctane 0.91 (Simplify your answers. Use integers or decimals for any numbers in the expression.)1) NABH, 2) H3O* O no reaction OH HO TH. HOCH H HOW . H H CH(CH,l