H H Predict the splitting pattern predicted for the circled proton in the structure below. Consider complex coupling and long-range coupling. CH A d B dd C dt HO D ddt E dq
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- Can you please help me with this ochem question?Please don't provide handwriting solutionBr Predict the splitting pattern predicted for the circled proton in the structure below. Consider complex coupling and long-range coupling. A) d Question 27 of 33 B) dd HH ***||| O H Br Submit Tap here or pull up for additional resources OH
- Draw the structure next to the matching spectrum and mark the peaks on the spectra that helped you pick that compoundH3CO Predict the splitting pattern expected for the circled proton in the structure below. Consider complex coupling and long-range coupling. O --+- H H H A) d B) dd C) dt D) ddt E) dq +NMR Spectroscopy Structure & reasoning
- Can you explain spectroscopy? Let's start with NMR Spectroscopy. What is the difference between a proton being enantiotopic and homotopic? What does it mean for a proton to be shielded or deshielded? How do you determine J (the coupling constant)? What does 'coupling is mutual' mean? How is that translated on the NMS Spectroscopy spectrum? Does that have to do with the polarity of the molecule? Is there an easier way to explain that? When thinking about C-13 NRM Spectroscopy, what it meant by the statement, "the carbons cannot integrate"? When looking at an NMR Spectroscopy spectrum, how do you know which peak belongs to which proton? (The intensity of the peak and the ppm of the peak) P.S. These questions come from after watching a lecture. There is no graded assignment attached to these questions. I simply do not understand the material.1) Indicate chemically equivalent nuclei (e.g. Ha, H³, Hc). 2) Estimate the chemical shifts on the following hydrogens. 3) Indicate the ratio of the area under the peaks 4) Indicate the Spin Spin splitting (singlet, doublet, triplet, etc) 1, 1, 2 tribromoethane Ethyl benzene Methyl isopropyl ketone Isopropyl propionatePredict the spin-spin coupling (aka splitting) by providing the multiplicity (singlet, doublet, triplet, doublets of doublet, quartet. etc.) of Ha, Hb, Hc, and Hd of the molecules below. Please decide how many non-equivalent protons in each given molecule.
- Which are true/false ?When we perform Bradford Assay to measure protein concentration, the spectrophotometer is set 595 nm because: a. the excitation peak of Coomassie Blue is best observed at 595 nm b. when Coomassie Blue binds to proteins, its maximum absorbance shifts to 595 nm c. the reducing effects of Coomassie Blue shifts the protein's maximum absorbance to 595 nm d. myoglobin is best observed at 595 nm1) a) When CO becomes coordinated to BH3, its stretching frequency increases, but when CO is coordinated to Ni(CO)3, its stretching frequency decreases. Explain. b) Does the stretching frequency of CO increase of decrease when (explain too) i) L of L M-CO becomes more electron withdrawing. ii) CO of L₁M-CO becomes coordinated to a Lewis acid, A, to become LM-CO-A 18