SO2 can be defined SO2 can be defined by the Van der Waals equation ( e and f only) ( A, B, C and D have posted answers)A=Vc=.171 L/molTc=428.91 KPc=78.20 barb= 34.93 barC=34.934d= Z=1 SO2 can be defined by the Van der Waals equation of state with constants a == 6.86 bar*L2/mol?and b = 0.057 L/mol.What are Pc, Tc, and Vc for the gas?а.b. What is the total pressure in bar for a 1.41M concentration of the gas at 298K. The gasconstant in terms of bar is given by R=0.08314 L*bar/(mol*K)С.Assume that SO2 acts as an ideal gas instead. Calculate the pressure under the sameconditions.d. Compare the pressures from the VdW equation and the Ideal Gas equation to obtain avalue for the compression factor, Z.From your value of Z, are the attractive forces or the repulsive forces larger under theseе.conditions.f.From your knowledge of the lewis structure of SO2, does your value of Z seemappropriate? Why or why not?

Answered: From your value of Z, are the…

Chemistry

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ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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SO₂ can be defined
SO₂ can be defined by the Van der Waals equation ( e and f only) ( A, B, C and D have posted answers)
A=
Vc=.171 L/mol
Tc=428.91 K
Pc=78.20 bar

b= 34.93 bar

C=34.934

d= Z=1

SO2 can be defined by the Van der Waals equation of state with constants a =
= 6.86 bar*L2/mol?
and b = 0.057 L/mol.
What are Pc, Tc, and Vc for the gas?
а.
b. What is the total pressure in bar for a 1.41M concentration of the gas at 298K. The gas
constant in terms of bar is given by R=0.08314 L*bar/(mol*K)
С.
Assume that SO2 acts as an ideal gas instead. Calculate the pressure under the same
conditions.
d. Compare the pressures from the VdW equation and the Ideal Gas equation to obtain a
value for the compression factor, Z.
From your value of Z, are the attractive forces or the repulsive forces larger under these
е.
conditions.
f.
From your knowledge of the lewis structure of SO2, does your value of Z seem
appropriate? Why or why not?

Expert Solution

Step 1

Z>1

Z is compressibilty factor

In this case attractive force more than repulsive force

Z<1

In this case attractive force is less than repulsive force

Z=1

Attractive force is equal to Repulsive force

e) From the Z value concluded that $\frac{P V}{n R T} = 1$ So attarctive force is equlas to repulsive force

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