Please correct answer and don't used hand raiting For the titration of 0.15 mol L-1 HNO2 with 0.10 mol L-1 NaOH, which of thefollowing indicators would be most suited to determine the equivalence point?(Ka(HNO2) = 5.6 x 10-4)Thymol Blue (pKa = 1.7)Methyl Red (pKa = 5.0)Alizarin Yellow R (pKa = 11.2)Phenyl Red (pKa = 7.9)Methyl Orange (pKa = 3.4)

A. Thymol Blue (pKa = 1.7)IncorrectThis indicator changes color at a pH much too acidic for this…

Answered: For the titration of 0.15 mol L-1 HNO2…

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter14: Principles Of Neutralization Titrations

Section: Chapter Questions

Problem 14.6QAP

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2. What is the pH at the equivalence point in the titration of 25.0 mL of 0.090 M phenol (Ka = 1.3 × 10−10) with 0.108 M NaOH? 7.00 5.65 8.98 11.29
Malonic acid (HO2CCH2CO2H) is a diprotic acid. In the titration of malonic acid w ith NaOH, stoichiometric points occur at pH = 3.9 and 8.8. A 25.00-mL sample of malonic acid of unknown concentration is titrated with 0.0984 M NaOH, requiring 31.50 mL of the NaOH solution to reach the phenolphthalein end point. Calculate the concentration of the initial malonic acid solution. (Sec Exercise 113.)
Sketch two pH curves, one for the titration of a weak acid with a strong base and one for a strong acid with a strong base. How are they similar? How are they different? Account for the similarities and the differences.
Given three acid-base indicatorsâ€”methyl orange (end point at pH 4), bromthymol blue (end point at pH 7), and phenolphthalein (end point at pH 9)â€”which would you select for the following acid-base titrations? (a) perchloric acid with an aqueous solution of ammonia (b) nitrous acid with lithium hydroxide (c) hydrobromic acid with strontium hydroxide (d) sodium fluoride with nitric acid
Phenolphthalein is a commonly used indicator that is colorless in the acidic form (pH 8.3) and pink in the base form (pH 10.0). It is a weak acid with a pKa of 8.7. What fraction is in the acid form when the acid color is apparent? What fraction is in the base form when the base color is apparent?
Consider the following pH curves for 100.0 mL of two different acids with the same initial concentration each titrated by 0.10 M NaOH. a. Which plot represents a pH curve of a weak acid, and which plot is for a strong acid? How can you tell? Cite three differences between the plots that help you decide. b. In both cases the pH is relatively constant before the pH changes greatly. Does this mean that at some point in each titration each solution was a buffered solution? c. True or false? The equivalence point volume for each titration is the same. Explain your answer. d. True or false? The pH at the equivalence point for each titration is the same. Explain your answer.
Consider the following two acids: pKa1 = 2.98; pKa2 = 13.40 HO2CCH2CH2CH2CH2CO2H Adipic acid pKa1 = 4.41; pKa2 = 5.28 In two separate experiments the pH was measured during the titration of 5.00 mmol of each acid with 0.200 M NaOH. Each experiment showed only one stoichiometric point when the data were plotted. In one experiment the stoichiometric point was at 25.00 mL added NaOH, and in the other experiment the stoichiometric point was at 50.00 mL NaOH. Explain these results.
Calculate the pH change when 10.0 mL of 0.100-M NaOH is added to 90.0 mL pure water, and compare the pH change with that when the same amount of NaOH solution is added to 90.0 mL of a buffer consisting of 1.00-M NH3 and 1.00-M NH4Cl. Assume that the volumes are additive. Kb of NH3 = 1.8 × 10-5.
Lactic acid is a common by-product of cellular respiration and is often said to cause the burn associated with strenuous activity. A 25.0-mL sample of 0.100 M lactic acid (HC3H5O3, pKa = 3.86) is titrated with 0.100 M NaOH solution. Calculate the pH after the addition of 0.0 mL, 4.0 mL, 8.0 mL, 12.5 mL, 20.0 mL, 24.0 mL, 24.5 mL, 24.9 mL, 25.0 mL, 25.1 mL, 26.0 mL, 28.0 mL, and 30.0 mL of the NaOH. Plot the results of your calculations as pH versus milliliters of NaOH added.
When 40.00 mL of a weak monoprotic acid solution is titrated with 0.100-M NaOH, the equivalence point is reached when 35.00 mL base has been added. After 20.00 mL NaOH solution has been added, the titration mixture has a pH of 5.75. Calculate the ionization constant of the acid.
In the titration of 50.00 mL 0.0200M weak base B using 0.0150 M HCI, which indicator is the best one to be used? (pK, of the weak base B is 10.50). Indicator 2: Methyl red: pH transition = 4.8-6.0 Indicator 1: Cresol purple: pH transition = 1.2-2.8 Indicator 4: Thymolthalein: pH transition = 8.5-10.5 O Indicator 5: Indigo Carmine: pH transition= 11.6- 14.0 O Indicator 3: Cresol red: pH transition = 7.2-8.8
In the titration of 50.00 mL 0.0200M weak base B using 0.0150 M HCI, which indicator is the best one to be used? (pK, of the weak base B is 10.50). Indicator 4: Thymolthalein: pH transition = 8.5-10.5 OIndicator 5: Indigo Carmine: pH transition= 11.6- 14.0 Indicator 3: Cresol red: pH transition 7.2-8.8 Indicator 1: Cresol purple: pH transition = 1.2-2.8 Indicator 2: Methyl red: pH transition = 4.8-6.0

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