BrCH₂ONaCH₂OH?a. Identify the type of alkyl halide:b. Identify the type of nucleophile/base:c. Predict the anticipated mechanism:d. Draw the predicted mechanism(s). If more than one product is possible for a mechanism,draw the mechanism for each product.2. For the following reaction:CH2CH₂ONaBr CH₂CH₂OH?a. Identify the type of alkyl halide:b. Identify the type of nucleophile/base:c. Predict the anticipated mechanism:d. Draw the predicted mechanism(s). If more than one product is possible for a mechanism,draw the mechanism for each product.

Answered: Image /qna-images/answer/79631e01-9c8c-43f0-bc3a-582cda6149f0.jpg

Answered: Br CH₂ONa CH₂OH ? a. Identify the type…

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter13: Substitution

Section: Chapter Questions

Problem 8E

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Draw the products of each reaction, and label the nucleophile and electrophile. (see the attachment)
b. d. a. a 6. Draw the organic product formed for each reaction. COOH COOH A [1] LDA [2] CH3CH₂l [1] Br₂. CH3CO₂H [2] Li₂CO3. LiBr. DMF 12 (excess) TOH CN NaH Br₂ (excess) TOH + CHI3
For each of the reactions indicate which reactant is the nucleophile and which is the electrophile.
The reaction will proceed with mechanism because the secondary alkyl halide react with nucleophile. + NaOCH3 Br CH3 O a. SN2, strong O b. SN1, strong O c. SN1, weak O d. SN2, weak
Draw the products of each reaction, and label the nucleophile and electrophile.
1. Draw the products of each nucleophilic substitution reaction a. b. D b OH C. d. e. f. Br 1 NaCN + NaOCH3 H₂O
Rank the species in each group in order of increasing nucleophilicity. a. CH,, "OH, "NH2 b. H20, OH, "SH in CH3OH c. CH,CH2S", CH;CH2O¯, CH;COO" in CH3OH d. CH3NH2, CH3SH, CH;OH in acetone e. "OH, F", CI" in acetone f. HS, F", CI in CH3OH
Draw the products of each reaction. NH3 [1] NH,CI, NaCN a. BrCH,COOH Тarge excess c. CH,CH,CH(CH,)CHO [2] H30* H [1] NaOEt [1) N2OE! b. CH;CONH--cOOEt ČOOEt [2] (CH3),CHCI [3] H3O*, A d. CH;CONH-C-cOOEt cOOEt [2] BRCH,CO,Et [3] H3O*, A
Draw the products of each reaction.
Draw the substitution product that results when CH,CH2CH;CH,Br reacts with each nucleophile. d. "OCH(CH3)2 e. "C=CH f. H20 a. "OH g. NH3 b. "SH h. Nal c. "ČN i. NaNg
Draw the full electron pushing mechanism for the reaction depicted including ALL intermediates (with lone pairs and formal charges). Clearly label the electrophile and nucleophile in each step where appropriate.
Question one parts A though c a. Which product forms from the following reaction? Answer as letter choice only (i.e., "E" not "E.") CHO HOH HOH H OH H OH CHOH Brs. H0 ??? A. В. C. D. COOH HOH HOH H OH HOH CHOH CH-OH CHO COOH но HO HOH H OH HOH ČOOH HO -H но HO H H OH HOH CHOH HOH H OH COOH b. Which of the following structures shows the Haworth configuration in the alpha configuration of the beginning sugar? Answer as letter choice only (ie. "E" not "E."). сно HO-H HO H Намorth Form Alpha Configuration H- OH нон CHOH B. A. CH,OH CH,OH CH,OH CH,OH OH OH OH O OH OH OP OH он он он OH C. Answer the following question. What is the expected product of this reaction? CHO H- -Он NABH, HO-H H- ??? OH H- -OH ČH,OH 運運重 А. В. С. CH,OH COOH COOH H- HO-H H- OH -OH OH но- но H- H- H OH H- OH OH HHOH H- ČH-OH H- -OH ČH,OH COOH

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