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explain in short terms the following vocab: exact mass, elemental analysis, mass spectrometry and their applications
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- Calculate the number of atoms of hydrogen (H) in 323 cm3 of the colorless gas ethylene at 0 °C and atmospheric pressure, where its density is 1.25×10-3 g cm-3. The molecular formula of ethylene is C2H4.*(iii) The reaction of ethene with aqueous potassium manganate(VII), KMNO., produces ethane-1,2-diol, CH,OHCH,OH. Data: molar mass of ethane-1,2-diol = 62 g mol In an experiment, KMNO, containing only "O reacts with ethene. Suggest how the mass spectrum of ethane-1,2-diol data could be used to decide whether the oxygen atoms in ethane-1,2-diol came from the manganate(VII) ion, water, or a combination of the two. (2)Potentially Useful Information Spectrochemical Series: I < Br < SCN < Cl` < NO3¯ < F° < OH° < C2O4² ~ H2O < NCS“ < NH3 < en < PPH3 A student has three test tubes containing a metal (M) nitrate solution M(NO3)2 (aq) (where "M" represents a generic transition metal). The student adds aqueous ammonia (NH3) to one test tube, aqueous hydrochloric acid (HCI) to the second tube, and nothing more to the third tube, but forgets to label the tubes. After this, one test tube contains a red solution, one an orange solution, and one a yellow solution. Note: This metal, M, would follow the same rules that we used for Cu(II), Ni(II), and Co(II). The Jahn-Teller Effect does not apply. Complete each statement or answer each question below about the solutions in the three test tubes. The coordination complex formed by adding HCI to the metal solution has a coordination number of... O 3 2
- Calculate the number of atoms of carbon (C) in 475 cm3 of the colorless gas butane at 0 °C and atmospheric pressure, where its density is 2.59×10-3 g cm-3. The molecular formula of butane is C4H10.Potentially Useful Information Spectrochemical Series: I < Br < SCN° < Cl° < NO3¯ < F < OH° < C2O4²-~ H2O < NCS < NH3 < en < PPH3 A student has three test tubes containing a metal (M) nitrate solution M(NO3)2 (aq) (where "M" represents a generic transition metal). The student adds aqueous ammonia (NH3) to one test tube, aqueous hydrochloric acid (HCI) to the second tube, and nothing more to the third tube, but forgets to label the tubes. After this, one test tube contains a red solution, one an orange solution, and one a yellow solution. Note: This metal, M, would follow the same rules that we used for Cu(II), Ni(II), and Co(II). The Jahn-Teller Effect does not apply. Complete each statement or answer each question below about the solutions in the three test tubes. The coordination complex causing the orange solution causes a larger splitting between the d orbitals of the metal then the coordination complex causing the... O red solution. O yellow solution. What color light does the…alculate (to the nearest 0.1 u) the formula mass of these compounds. (a) rubidium nitrate, RbNO3 u(b) carbon tetrachloride, CCl4 u(c) boron trifluoride, BF3 u Calculate (to the nearest 0.1 u) the formula mass of these compounds. (a) azithromycin, C38H72N2O12 u(b) saccharin, C7H5NO3S u(c) glucose, C6H12O6 u
- 2. The solubility of aspirin in water is 1 g per 300 mL at 25 °C. Assuming that your crystallization and washing with water were done at this temperature, what weight of aspirin did you lose in the filtrate and washings? How much was your percent yield lowered by this loss?2. Balance the following equations by supplying the lowest whole numbers for w, x, y, and z: (a) w S8 + x Cl₂ → y S₂Cl₂ (b) w C3H8O + x O₂ → y CO₂ + z H₂O (c) w Fe + x H₂O → y Fe₂O3 + z H₂The formula of the hydrate of magnesium sulfate was determined (M9SO4.XH20) and the following data was obtained. Mass of crucible + lid + unknown 6.0236 g Mass of crucible + lid 4.0002 g Mass of unknown hydrate Mass of crucible + lid + residue: after 1 st heating 5.0842 g after 2 nd heating 5.0426g after 3 rdheating 5.0339g Mass of water lost Mass of anhydrous salt Percent Water in unknown hydrate Moles of water in hydrate sample Moles of anhydrous salt in hydrate sample Calculated Mole ratio(H2O: salt)_ Complete formula of the hydrate
- Suppose you are hired by the Environmental Protection Agency as an engineer to measure sulfur dioxide (SO2) emissions in a small industrial power plant. And suppose you analyze a gas sample and get the following composition: 75.66% N2, 10.24% CO2, 8.27% H2O, 5.75% O2, and 0.0825% SO2. You show these figures to the factory clerk the next day, and he insists that this analysis is erroneous and states that the fuel is natural gas, contains methane and ethane and does not contain sulfur. You ask if another fuel is used, and sometimes they say they use fuel as fuel, but at the time of analysis they say that this fuel is not used. However, your measurements show that the enterprise is using fuel at the time of measurement, and the responsible person accepts this later and accepts that they have made mistakes.a) Calculate the molar ratio of carbon / hydrogen in the fuel and use the result to prove that the fuel cannot be natural gas.b) Assuming that C, H and S are the elements present in the…Calculate the average atomic mass of Amazium, a newly discovered element (Amazium, symbol Az) which is determined by mass spectrometry to have two isotopes with the following masses and percent (%) composition (abundance) Show work.The organic salt tetrabutylammonium hexafluorophosphate is widely used as a non-aqueous electrolyte in electrochemistry. Its chemical formula is C16H36F6NP. Determine a) its molecular weight (in g/mol); b) the mass% of hydrogen; and c) the mass% of fluorine. Molar Mass: C=16, H=1, F=19, N=14, P=31
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