Principle: Direct permanganometry The percentage purity of hydrogen peroxide set by the USP is 2.5 – 3.5 g/100 ml. Procedure (whole formulation; three trials) 1. Pipet 2 milliters of hydrogen peroxide solution into a suitable flask containing 20 milliters of water. (H;O2 p = 1.45 g/ml) 2. Add 20 milliters of diluted sulfuric acid 3. Titrate with 0.1 N potassium permanganate solution, wheremi was consumed (the theoretical volume consumed for each trial is provided in the table below). 4. Calculate the percentage purity of the sample, using the formula: NI mi x meg 100 % % = Reaction (fil in the coefficients on the blank spaces): _H2O2 +_ KMNO4 + _ H;SO4 →_ O2 + _ MNSO, + _ K2SO4 + _ H20 Oxidation: Reducing Agent H2*1022 → 0,0 + 2H +_• Reduction: Oxidizing Agent Mn*70r² + 8H + _* → Mn*7 + 4H2O * Number of e- gain/loss of oxygen is, ; which is the factor hydrogen peroxide Data and Results: Trial 1 Trial 2 Trial 3 Weight of H:Oa Volume of KMNO, Percentage purity Average percentage purity 43 ml 42.8 ml 43.5 ml Calculation and Conclusion
Principle: Direct permanganometry The percentage purity of hydrogen peroxide set by the USP is 2.5 – 3.5 g/100 ml. Procedure (whole formulation; three trials) 1. Pipet 2 milliters of hydrogen peroxide solution into a suitable flask containing 20 milliters of water. (H;O2 p = 1.45 g/ml) 2. Add 20 milliters of diluted sulfuric acid 3. Titrate with 0.1 N potassium permanganate solution, wheremi was consumed (the theoretical volume consumed for each trial is provided in the table below). 4. Calculate the percentage purity of the sample, using the formula: NI mi x meg 100 % % = Reaction (fil in the coefficients on the blank spaces): _H2O2 +_ KMNO4 + _ H;SO4 →_ O2 + _ MNSO, + _ K2SO4 + _ H20 Oxidation: Reducing Agent H2*1022 → 0,0 + 2H +_• Reduction: Oxidizing Agent Mn*70r² + 8H + _* → Mn*7 + 4H2O * Number of e- gain/loss of oxygen is, ; which is the factor hydrogen peroxide Data and Results: Trial 1 Trial 2 Trial 3 Weight of H:Oa Volume of KMNO, Percentage purity Average percentage purity 43 ml 42.8 ml 43.5 ml Calculation and Conclusion
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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This is a practice problem.
![Experiment 1. Assay of Hydrogen Peroxide Solution
Principle:
Direct permanganometry
The percentage purity of hydrogen peroxide set by the USP is 2.5 – 3.5 g/100 ml.
Procedure (whole formulation; three trials)
1. Pipet 2 milliters of hydrogen peroxide solution into a suitable flask containing 20 militers of water. (H;O2 p = 1.45 g/ml)
2. Add 20 milliliters of diluted sulfuric acid
3. Titrate with 0.1 N potassium permanganate solution, where
for each trial is provided in the table below).
ml was consumed (the theoretical volume consumed
NI ml x meg
4. Calculate the percentage purity of the sample, using the formula:
% =
x 100 %
wt
Reaction (fill in the coefficients on the blank spaces):
_H2O2 +_ KMNO4 +_ H2SO4 → _O2 +_ MNSO4 + _ K2SO4 + _ H2o
Oxidation: Reducing Agent H2*1022
O20 + 2H +_e-
Reduction: Oxidizing Agent Mn*O2 + 8H +.
e- Mn*7 + 4H2O
Number of e- gain/loss of oxygen is
; which is the factor hydrogen peroxide
-
Data and Results:
Trial 1
Trial 2
Trial 3
Weight of H2O2
Volume of KMNO.
Percentage purity
Average percentage purity
43 ml
42.8 ml
43.5 ml
Calculation and Conclusion
On space below, solve the titer value and average percentage purity of the sample then interpret.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F59b472b7-7944-4d7e-bd2a-377808f8a955%2F277850e9-a5c4-4e84-9f40-25fac7967f78%2Ftjwv87_processed.png&w=3840&q=75)
Transcribed Image Text:Experiment 1. Assay of Hydrogen Peroxide Solution
Principle:
Direct permanganometry
The percentage purity of hydrogen peroxide set by the USP is 2.5 – 3.5 g/100 ml.
Procedure (whole formulation; three trials)
1. Pipet 2 milliters of hydrogen peroxide solution into a suitable flask containing 20 militers of water. (H;O2 p = 1.45 g/ml)
2. Add 20 milliliters of diluted sulfuric acid
3. Titrate with 0.1 N potassium permanganate solution, where
for each trial is provided in the table below).
ml was consumed (the theoretical volume consumed
NI ml x meg
4. Calculate the percentage purity of the sample, using the formula:
% =
x 100 %
wt
Reaction (fill in the coefficients on the blank spaces):
_H2O2 +_ KMNO4 +_ H2SO4 → _O2 +_ MNSO4 + _ K2SO4 + _ H2o
Oxidation: Reducing Agent H2*1022
O20 + 2H +_e-
Reduction: Oxidizing Agent Mn*O2 + 8H +.
e- Mn*7 + 4H2O
Number of e- gain/loss of oxygen is
; which is the factor hydrogen peroxide
-
Data and Results:
Trial 1
Trial 2
Trial 3
Weight of H2O2
Volume of KMNO.
Percentage purity
Average percentage purity
43 ml
42.8 ml
43.5 ml
Calculation and Conclusion
On space below, solve the titer value and average percentage purity of the sample then interpret.
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