EPR. Analyze the EPR spectrum below for Cu(TPP)a. Note that ligand splitting is not observed. (TPP = tetraphenylporphyrin) a. Label g, and gı- b. The geometry of the compound is square planar. Draw the compound and explain the multiplicity observed in the EPR spectrum. Cu (I = 3/2) 2500.00 2680.00 2860.00 3040.00 3220.00 3400.00 Magnetic Field (G) Intensity

EPR. Analyze the EPR spectrum below for Cu(TPP)a. Note that ligand splitting is not observed. (TPP = tetraphenylporphyrin) a. Label g, and gı- b. The geometry of the compound is square planar. Draw the compound and explain the multiplicity observed in the EPR spectrum. Cu (I = 3/2) 2500.00 2680.00 2860.00 3040.00 3220.00 3400.00 Magnetic Field (G) Intensity

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Triphenylphosphine as a free ligand shows a 3¹P NMR signal at -4 ppm. Cis-Pt(PPh3)2Cl2 shows a single resonance at +12 ppm. Cis-Pd(PPh3)2Cl2 shows a single resonance at +24 ppm. Give a plausible explanation as to why the 31P resonance in the Pd complex is shifted to a more deshielded position than in the Pt complex. (Hint: check the periodic table)
600 - 15300 400 200 5800 25 000 20 000 15 000 10 000 5 000 Frequency (cm-1) Answer the following questions for both complexes: (ii) Draw the suitable Orgel diagrams and show the observed absorptions,
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Fill in the space below with DIGITS only. The condition for a complex to be low spin; from the coupling energy of the crystal field cleavage energy of this complex. Gap 1. Fill the blanks, read the relevant text. large (1) / small (2).
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Hi,kindly reply with quick,correct and accurate answers, working and drawing. Thank you so much. I will give helpful rating. b) Consider (Co(CI)e and (Co(NHs))e]* ions. i. Illustrate the energy level splitting diagram for both complexes. ii. Show the number of unpaired electron and the spin type of each of the complex ion.
please skip if you already answered this. I will upvote if this is typewritten. much appreciated. thank you so much NOTE: THE BIG NUMBER IS FOR NUMBERING ONLY. IT IS NOT GRADED