Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Some different views of an octahedral symmetry metal complex
1
3
1
3
6
3
2 1
4
2
2
View down a C, axis
View down a C, axis
View down a C, axis
On
E 8C3
6C2 6C, 3C,
i 6S, 8S, 30, 604
A1g
1
1
1
1
1
1
1
1
1
-1
-1
1
Azg
1
-1
1
-1
z², x² - y?
Eg
2
-1
-1
Tig
-1
-1
-1
1
-1
T2g
(xy, xz, yz)
1
-1
-1
-1
-1
A1u
-1
-1
-1
-1
1
1
1
-1
A2u
1
1
-1
-1
-1
-1
-1
1
E
-1
-2
1
-2
3
-1
1
-1
-3
-1
(x, y, z)
3
Tzu
-1
-1
-3
1
1
-1
The octahedral character table above may be useful for the following questions.
1.
1.
2.
3.
3.
2.
3.
3.
1.
2.
![Using octahedral symmetry, match each ligand SALC with its most likely interaction with a meta
within the Lewis acid/base model.
(The Generic Octahedral Metal Complex information above may be useful in doing this.)
Eg symmetry SALC (ligand = NH3)
V[Choos
Pi Base
Sigma Base
Eg symmetry SALC (ligand = 1-)
Pi Acid
Sigma Acid
T2g symmetry SALC (ligand = 1-)
[ Choose ]
T2g symmetry SALC (ligand = CO)
%3D
[ Choose ]
>](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F24512ff8-b210-4e56-b993-d77459234509%2F317221fb-5a8e-4358-bf21-d96b4b4697ed%2F0raumk_processed.png&w=3840&q=75)
Transcribed Image Text:Using octahedral symmetry, match each ligand SALC with its most likely interaction with a meta
within the Lewis acid/base model.
(The Generic Octahedral Metal Complex information above may be useful in doing this.)
Eg symmetry SALC (ligand = NH3)
V[Choos
Pi Base
Sigma Base
Eg symmetry SALC (ligand = 1-)
Pi Acid
Sigma Acid
T2g symmetry SALC (ligand = 1-)
[ Choose ]
T2g symmetry SALC (ligand = CO)
%3D
[ Choose ]
>
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