Some different views of an octahedral symmetry metal com

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
Some different views of an octahedral symmetry metal complex
1
3
1
3
6
3
2 1
4
2
2
View down a C, axis
View down a C, axis
View down a C, axis
On
E 8C3
6C2 6C, 3C,
i 6S, 8S, 30, 604
A1g
1
1
1
1
1
1
1
1
1
-1
-1
1
Azg
1
-1
1
-1
z², x² - y?
Eg
2
-1
-1
Tig
-1
-1
-1
1
-1
T2g
(xy, xz, yz)
1
-1
-1
-1
-1
A1u
-1
-1
-1
-1
1
1
1
-1
A2u
1
1
-1
-1
-1
-1
-1
1
E
-1
-2
1
-2
3
-1
1
-1
-3
-1
(x, y, z)
3
Tzu
-1
-1
-3
1
1
-1
The octahedral character table above may be useful for the following questions.
1.
1.
2.
3.
3.
2.
3.
3.
1.
2.
Transcribed Image Text:Some different views of an octahedral symmetry metal complex 1 3 1 3 6 3 2 1 4 2 2 View down a C, axis View down a C, axis View down a C, axis On E 8C3 6C2 6C, 3C, i 6S, 8S, 30, 604 A1g 1 1 1 1 1 1 1 1 1 -1 -1 1 Azg 1 -1 1 -1 z², x² - y? Eg 2 -1 -1 Tig -1 -1 -1 1 -1 T2g (xy, xz, yz) 1 -1 -1 -1 -1 A1u -1 -1 -1 -1 1 1 1 -1 A2u 1 1 -1 -1 -1 -1 -1 1 E -1 -2 1 -2 3 -1 1 -1 -3 -1 (x, y, z) 3 Tzu -1 -1 -3 1 1 -1 The octahedral character table above may be useful for the following questions. 1. 1. 2. 3. 3. 2. 3. 3. 1. 2.
Using octahedral symmetry, match each ligand SALC with its most likely interaction with a meta
within the Lewis acid/base model.
(The Generic Octahedral Metal Complex information above may be useful in doing this.)
Eg symmetry SALC (ligand = NH3)
V[Choos
Pi Base
Sigma Base
Eg symmetry SALC (ligand = 1-)
Pi Acid
Sigma Acid
T2g symmetry SALC (ligand = 1-)
[ Choose ]
T2g symmetry SALC (ligand = CO)
%3D
[ Choose ]
>
Transcribed Image Text:Using octahedral symmetry, match each ligand SALC with its most likely interaction with a meta within the Lewis acid/base model. (The Generic Octahedral Metal Complex information above may be useful in doing this.) Eg symmetry SALC (ligand = NH3) V[Choos Pi Base Sigma Base Eg symmetry SALC (ligand = 1-) Pi Acid Sigma Acid T2g symmetry SALC (ligand = 1-) [ Choose ] T2g symmetry SALC (ligand = CO) %3D [ Choose ] >
Expert Solution
steps

Step by step

Solved in 2 steps

Blurred answer
Knowledge Booster
Symmetry Elements of Objects
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY