7. Calculate [Fe³*] in the solution prepared in step 12 of the procedure.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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PART 3: DETERMINATION OF AN EQUILIBRIUM CONSTANT
TABLE 2 - COMPOSITION OF SOLUTIONS REQUIRED FOR CALCUATION OF EQUILIBRIUM CONSTANT
Volume of 0.002 mol L-1
Volume of 0.002 mol L1
Flask #
Fe(NO:):(aq) / mL
Book1
Excel
KSCN(aq) / mL
0.00
20.00 (10 + 10)
7 (blank)
25.00
File
Home Insert Page Layou Forn
8.
25.00
9.
25.00
25.00
A
%
10
25.00
35.00 (25 + 10)
50.00 (25 + 25)
11
25.00
Clipboard
Font
Alignment Number
12.
Pipette 5.00 mL of 0.2 mol L1 Fe(NO3)3(aq) into a clean 500.0-mL volumetric flask. Fill the flask carefully to
the calibration mark with 1.0 mol L HNO:(aq), stopper it, and mix well by inversion (25 times). Pour about
175 mL of the solution that you just prepared into a clean, dry 250-mL beaker. The concentration of
10
fe
Fe(NO:):(aq) in this solution is approximately 0.002 mol L'1.
Pipette the required volumes of 0.002 mol L1 Fe(NO:):(aq) into flasks 7 to 11. Using the burette, transfer the
required volume of KSCN(aq) (record the burette readings) into flask 8 only. Make flasks 7 and 8 up to the
marks with deionized water and mix them by inversion (25 times each). The solution in flask 7 is the blank.
Measure the absorbance of the solution 8, three times, using the same procedure that you used when you were
13.
A
B
E
sample R1
R2
R3
AVS
1
2
7
3
8
0.127
0.128
0.127
0.127
14.
4
0.169
0.165
0. 165
0.166
measuring the solutions in Part 2. Remember to use a fresh portion of solution for each measurement and zero
5
10
0.222
0.222
0.222
0.222
the instrument with the blank solution 7.
11
0.308
0.308
0.308
0.308
15.
Repeat the solution preparation and absorbance measurement for flasks 9, 10, and 11, one at a time. At the
end you should have three absorbance measurements for each solution.
Measure the temperature of the solution remaining in one of the flasks. Thermometers are in a white tray on
...
...
16.
Ready
the front demonstration bench.
Transcribed Image Text:PART 3: DETERMINATION OF AN EQUILIBRIUM CONSTANT TABLE 2 - COMPOSITION OF SOLUTIONS REQUIRED FOR CALCUATION OF EQUILIBRIUM CONSTANT Volume of 0.002 mol L-1 Volume of 0.002 mol L1 Flask # Fe(NO:):(aq) / mL Book1 Excel KSCN(aq) / mL 0.00 20.00 (10 + 10) 7 (blank) 25.00 File Home Insert Page Layou Forn 8. 25.00 9. 25.00 25.00 A % 10 25.00 35.00 (25 + 10) 50.00 (25 + 25) 11 25.00 Clipboard Font Alignment Number 12. Pipette 5.00 mL of 0.2 mol L1 Fe(NO3)3(aq) into a clean 500.0-mL volumetric flask. Fill the flask carefully to the calibration mark with 1.0 mol L HNO:(aq), stopper it, and mix well by inversion (25 times). Pour about 175 mL of the solution that you just prepared into a clean, dry 250-mL beaker. The concentration of 10 fe Fe(NO:):(aq) in this solution is approximately 0.002 mol L'1. Pipette the required volumes of 0.002 mol L1 Fe(NO:):(aq) into flasks 7 to 11. Using the burette, transfer the required volume of KSCN(aq) (record the burette readings) into flask 8 only. Make flasks 7 and 8 up to the marks with deionized water and mix them by inversion (25 times each). The solution in flask 7 is the blank. Measure the absorbance of the solution 8, three times, using the same procedure that you used when you were 13. A B E sample R1 R2 R3 AVS 1 2 7 3 8 0.127 0.128 0.127 0.127 14. 4 0.169 0.165 0. 165 0.166 measuring the solutions in Part 2. Remember to use a fresh portion of solution for each measurement and zero 5 10 0.222 0.222 0.222 0.222 the instrument with the blank solution 7. 11 0.308 0.308 0.308 0.308 15. Repeat the solution preparation and absorbance measurement for flasks 9, 10, and 11, one at a time. At the end you should have three absorbance measurements for each solution. Measure the temperature of the solution remaining in one of the flasks. Thermometers are in a white tray on ... ... 16. Ready the front demonstration bench.
17. Calculate [Fe³3-] in the solution prepared in step 12 of the procedure.
|8. Calculate the average absorbance values for solutions 8 to 11.
9. Use the equation for the calibration curve's line of best fit and the average absorbance values to determine
[FESCN2-], at equilibrium, in each solutions 8 to 11.
10. Calculate the initial [Fe³*] and initial [SCN-] in solutions 8 to 11.
11. Place the results from calculations 9 and 10 into individual ICE tables. Calculate the equilibrium concentration of
Fe3+ and SCN- in solutions 8 to 11.
Transcribed Image Text:17. Calculate [Fe³3-] in the solution prepared in step 12 of the procedure. |8. Calculate the average absorbance values for solutions 8 to 11. 9. Use the equation for the calibration curve's line of best fit and the average absorbance values to determine [FESCN2-], at equilibrium, in each solutions 8 to 11. 10. Calculate the initial [Fe³*] and initial [SCN-] in solutions 8 to 11. 11. Place the results from calculations 9 and 10 into individual ICE tables. Calculate the equilibrium concentration of Fe3+ and SCN- in solutions 8 to 11.
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