Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question

Transcribed Image Text:PART 3: DETERMINATION OF AN EQUILIBRIUM CONSTANT
TABLE 2 - COMPOSITION OF SOLUTIONS REQUIRED FOR CALCUATION OF EQUILIBRIUM CONSTANT
Volume of 0.002 mol L-1
Volume of 0.002 mol L1
Flask #
Fe(NO:):(aq) / mL
Book1
Excel
KSCN(aq) / mL
0.00
20.00 (10 + 10)
7 (blank)
25.00
File
Home Insert Page Layou Forn
8.
25.00
9.
25.00
25.00
A
%
10
25.00
35.00 (25 + 10)
50.00 (25 + 25)
11
25.00
Clipboard
Font
Alignment Number
12.
Pipette 5.00 mL of 0.2 mol L1 Fe(NO3)3(aq) into a clean 500.0-mL volumetric flask. Fill the flask carefully to
the calibration mark with 1.0 mol L HNO:(aq), stopper it, and mix well by inversion (25 times). Pour about
175 mL of the solution that you just prepared into a clean, dry 250-mL beaker. The concentration of
10
fe
Fe(NO:):(aq) in this solution is approximately 0.002 mol L'1.
Pipette the required volumes of 0.002 mol L1 Fe(NO:):(aq) into flasks 7 to 11. Using the burette, transfer the
required volume of KSCN(aq) (record the burette readings) into flask 8 only. Make flasks 7 and 8 up to the
marks with deionized water and mix them by inversion (25 times each). The solution in flask 7 is the blank.
Measure the absorbance of the solution 8, three times, using the same procedure that you used when you were
13.
A
B
E
sample R1
R2
R3
AVS
1
2
7
3
8
0.127
0.128
0.127
0.127
14.
4
0.169
0.165
0. 165
0.166
measuring the solutions in Part 2. Remember to use a fresh portion of solution for each measurement and zero
5
10
0.222
0.222
0.222
0.222
the instrument with the blank solution 7.
11
0.308
0.308
0.308
0.308
15.
Repeat the solution preparation and absorbance measurement for flasks 9, 10, and 11, one at a time. At the
end you should have three absorbance measurements for each solution.
Measure the temperature of the solution remaining in one of the flasks. Thermometers are in a white tray on
...
...
16.
Ready
the front demonstration bench.
![17. Calculate [Fe³3-] in the solution prepared in step 12 of the procedure.
|8. Calculate the average absorbance values for solutions 8 to 11.
9. Use the equation for the calibration curve's line of best fit and the average absorbance values to determine
[FESCN2-], at equilibrium, in each solutions 8 to 11.
10. Calculate the initial [Fe³*] and initial [SCN-] in solutions 8 to 11.
11. Place the results from calculations 9 and 10 into individual ICE tables. Calculate the equilibrium concentration of
Fe3+ and SCN- in solutions 8 to 11.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ffe89836b-bba0-4df5-9667-e99956de1c6d%2F068780cc-d835-4436-9e28-7b4d8a103d15%2F1d5pq7z_processed.png&w=3840&q=75)
Transcribed Image Text:17. Calculate [Fe³3-] in the solution prepared in step 12 of the procedure.
|8. Calculate the average absorbance values for solutions 8 to 11.
9. Use the equation for the calibration curve's line of best fit and the average absorbance values to determine
[FESCN2-], at equilibrium, in each solutions 8 to 11.
10. Calculate the initial [Fe³*] and initial [SCN-] in solutions 8 to 11.
11. Place the results from calculations 9 and 10 into individual ICE tables. Calculate the equilibrium concentration of
Fe3+ and SCN- in solutions 8 to 11.
Expert Solution

This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
Step by step
Solved in 2 steps

Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning

Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education

Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning

Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY