Electronic StateΧ(ΙΣ)V/cm-1Vex/cm¹B./cm-1А (П1)384.29212.31.5012.390.11410.0843D./cm-14.03×10-8re/Å2.2095.4×10-82.6923A. What is the probability of a molecule being in the (v = 0, J = 10) level in the X electronic state at 300K?B. In the v = 0 level, which rotational level has the highest occupation probability (Jmp) at 300 K?C. Consider the (v" = 0 → v' = 1) vibrational transition in the X state of 135 Cl. Using Jmax from part (b),calculate the temperature (in Kelvin) at which the R(10) rovibrational line is three times more intensethan the R(Jmax) rovibrational line.D. The transition wavelength of the R(24) line in the X (v" = 0)→A (v' = 25) vibronic band is ex = 574.90nm. What is the X-A electronic energy offset, Tel (cm¯¹ units)?

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Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter27: Molecular Fluorescence Spectroscopy

Section: Chapter Questions

Problem 27.6QAP

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