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- Draw the structure of the major product of each reaction (If a racemic mixture is formed, indicate both enantiomers), and show the mechanismPlastic photochromic sunglasses are based on the following reversible rearrangement of a dye inside the lenses that occurs when the lenses are exposed to sunlight. The original dye absorbs UV light but not visible light and is thus colorless, while the rearrangement product absorbs visible light and is thus darkened. (a) Show the mechanism of the rearrangement. (b) Why does the rearrangement product absorb at a longer wavelength (visible light) than the original dye (UV)?When a 2, 6-disubstituted allyl phenyl ether is heated in an attempted Claisen rearrangement, migration occurs to give the p-allyl product as the result of two sequential pericyclic reactions. Explain.
- 15,18What would be the major product of the following reaction? O CH3 || C6H5C-CHCH3 + D20 A) B) C) D) E) O CD3 C6H5C-CHCH3 O CH3 1-1 C6H5C-CDCH3 O CH3 C6D5C-CDCH3 O CD3 | | C6H5C-CDCD3 OD - C6H5CDCHCH3 CH3 OD room temp. ?Draw the mechanism ffrom benzaldehyde to this using: i)NaBH4 ii)TsCl, py iii)NaCN iiii)H+, H2O
- Q6 Show how you would accomplish the follwoing transformations. (a) 2,2dibromobutane to but-1-yne (b) but-1-yne to oct-3-yne (c) trans-hex-2-ene to hex-2-yne (d) cyclodecyne to cis-cyclodecene (e) cyclodecyne to trans-cyclodecene (f) hex-1-yne to hexan-2-one, CH3COCH₂CH₂CH₂CH3 (g) hex-1-yn to hexanal, CH3(CH₂)4CHO (h) trans-hex-2-ene to cis-hex-2-ene6products x and y are? (draw structure)
- ONZ IS ON Determine which substitution mechanism occurs and draw the products, including stereochemistry. + -OCH3 DMSO Br H + CH3OH Br CH,CH, CH3Considering stereochemistry, draw the resulting E2 elimination product when H, is removed. H₂ H All H Br |||| X AJ U: S GDraw the structure of the major product of each reaction (If a racemic mixture is formed, indicate both enantiomers), and show the mechanism