Answered: Draw a molecular orbital (MO) energy…

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter6: Covalent Bonding

Section: Chapter Questions

Problem 112QRT

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a-Draw a molecular orbital (MO) energy level diagram for NO. Label the atomic orbitals, MOs and identify the frontier orbitals.

b-Explain the differences in bond dissociation energies and bond lengths on addition and removal
of an electron from NO.

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

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