15. How many electrons are in the two degenerate * molecular orbitals (MOs)? A. There are three electrons with one * MO being doubly occupied and the other singly occupied. B. There are two electrons with each * MO being singly occupied. C. There are two electrons that occupy one of the two * MOs. D. There are four electrons that occupy both * MOs. E. There is only one electron that occupies one of the two * MOs.

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter9: Bonding And Molecular Structure: Orbital Hybridization And Molecular Orbitals
Section: Chapter Questions
Problem 66SCQ: Lets look more closely at the process of hybridization. (a) What is the relationship between the...
icon
Related questions
icon
Concept explainers
Question
### Molecular Orbital Diagram of OF⁻

This diagram depicts the molecular orbital (MO) arrangement for the OF⁻ ion. Understanding this diagram helps explain the bonding and properties of oxygen-fluoride anions. Here's a breakdown of the components:

#### Atomic Orbitals
- **Oxygen (O)** and **Fluorine (F)** contribute individual atomic orbitals to form the molecular orbitals in OF⁻.
- These atomic orbitals are labeled as:
  - For Oxygen: \( 2s, 2p_x, 2p_y, 2p_z \)
  - For Fluorine: \( 2s, 2p_x, 2p_y, 2p_z \)

#### Molecular Orbitals
- Molecular orbitals are formed from the combination of the atomic orbitals from O and F.
- The molecular orbitals are labeled according to their type and energy levels, with sigma (\( \sigma \)) and pi (\( \pi \)) denoting bonding types.

1. **Sigma and Pi Bonding Orbitals:**
   - \( \sigma_{2s} \) and \( \sigma_{2s}^* \): Resulting from the combination of 2s orbitals.
   - \( \sigma_{2p_z} \): From the combination of \( 2p_z \) orbitals.
   - \( \pi_{2p_x} \) and \( \pi_{2p_y} \): From the combination of \( 2p_x \) and \( 2p_y \) orbitals respectively.

2. **Sigma and Pi Anti-bonding Orbitals:**
   - \( \pi_{2p_x}^* \) and \( \pi_{2p_y}^* \): Anti-bonding counterparts for \( \pi_{2p_x} \) and \( \pi_{2p_y} \).
   - \( \sigma_{2p_z}^* \): Anti-bonding counterpart for \( \sigma_{2p_z} \).

#### Energy Diagram
- The diagram is organized vertically with increasing energy from bottom to top.
- Solid horizontal lines indicate the relative energy levels of the orbitals.
- Dashed lines represent the hypothetical interactions and resulting volumes from the mixing of atomic orbitals to form molecular orbitals.

This visual representation is key for understanding the electronic configuration of OF⁻ and explaining
Transcribed Image Text:### Molecular Orbital Diagram of OF⁻ This diagram depicts the molecular orbital (MO) arrangement for the OF⁻ ion. Understanding this diagram helps explain the bonding and properties of oxygen-fluoride anions. Here's a breakdown of the components: #### Atomic Orbitals - **Oxygen (O)** and **Fluorine (F)** contribute individual atomic orbitals to form the molecular orbitals in OF⁻. - These atomic orbitals are labeled as: - For Oxygen: \( 2s, 2p_x, 2p_y, 2p_z \) - For Fluorine: \( 2s, 2p_x, 2p_y, 2p_z \) #### Molecular Orbitals - Molecular orbitals are formed from the combination of the atomic orbitals from O and F. - The molecular orbitals are labeled according to their type and energy levels, with sigma (\( \sigma \)) and pi (\( \pi \)) denoting bonding types. 1. **Sigma and Pi Bonding Orbitals:** - \( \sigma_{2s} \) and \( \sigma_{2s}^* \): Resulting from the combination of 2s orbitals. - \( \sigma_{2p_z} \): From the combination of \( 2p_z \) orbitals. - \( \pi_{2p_x} \) and \( \pi_{2p_y} \): From the combination of \( 2p_x \) and \( 2p_y \) orbitals respectively. 2. **Sigma and Pi Anti-bonding Orbitals:** - \( \pi_{2p_x}^* \) and \( \pi_{2p_y}^* \): Anti-bonding counterparts for \( \pi_{2p_x} \) and \( \pi_{2p_y} \). - \( \sigma_{2p_z}^* \): Anti-bonding counterpart for \( \sigma_{2p_z} \). #### Energy Diagram - The diagram is organized vertically with increasing energy from bottom to top. - Solid horizontal lines indicate the relative energy levels of the orbitals. - Dashed lines represent the hypothetical interactions and resulting volumes from the mixing of atomic orbitals to form molecular orbitals. This visual representation is key for understanding the electronic configuration of OF⁻ and explaining
**Question 15: Molecular Orbital Occupancy**

**How many electrons are in the two degenerate π<sub>2p</sub>* molecular orbitals (MOs)?**

A. There are three electrons with one π<sub>2p</sub>* MO being doubly occupied and the other singly occupied.  

B. There are two electrons with each π<sub>2p</sub>* MO being singly occupied.  

C. There are two electrons that occupy one of the two π<sub>2p</sub>* MOs.  

D. There are four electrons that occupy both π<sub>2p</sub>* MOs.  

E. There is only one electron that occupies one of the two π<sub>2p</sub>* MOs.
Transcribed Image Text:**Question 15: Molecular Orbital Occupancy** **How many electrons are in the two degenerate π<sub>2p</sub>* molecular orbitals (MOs)?** A. There are three electrons with one π<sub>2p</sub>* MO being doubly occupied and the other singly occupied. B. There are two electrons with each π<sub>2p</sub>* MO being singly occupied. C. There are two electrons that occupy one of the two π<sub>2p</sub>* MOs. D. There are four electrons that occupy both π<sub>2p</sub>* MOs. E. There is only one electron that occupies one of the two π<sub>2p</sub>* MOs.
Expert Solution
steps

Step by step

Solved in 2 steps with 1 images

Blurred answer
Knowledge Booster
Theories of Bonding
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781337399074
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781133949640
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781133611097
Author:
Steven S. Zumdahl
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry: An Atoms First Approach
Chemistry: An Atoms First Approach
Chemistry
ISBN:
9781305079243
Author:
Steven S. Zumdahl, Susan A. Zumdahl
Publisher:
Cengage Learning
Chemistry: Principles and Practice
Chemistry: Principles and Practice
Chemistry
ISBN:
9780534420123
Author:
Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:
Cengage Learning