Construct the reducible representation for vibration of the CO ligands in the molecule cis-W(CO)5. 2. Reduce the representation to a sum of rreducible representations. 3. Which of the representations are IR active in the C2v point group?
Construct the reducible representation for vibration of the CO ligands in the molecule cis-W(CO)5. 2. Reduce the representation to a sum of rreducible representations. 3. Which of the representations are IR active in the C2v point group?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Chemistry
1. Construct the reducible representation for vibration of the CO ligands in the molecule cis-W(CO)5.
2. Reduce the representation to a sum of rreducible representations.
3. Which of the representations are IR active in the C2v point group?
4. Assign the corresponding Millikan symbol to the IR bands in the spectra.
Transcribed Image Text:IR spectra of cis-(PPH3)2W(CO)4
100
90
80
70
60
50
2100
2050
2000
1950
1900
1850
1800
1750
Wavelength (cm^-1)
%Transmitance
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