Answer the following questions for square planar metal complexes ML4 (point group Dah): 1) determine the orbitals symmetries of the central metal atom and draw symmetry labelled molecular orbital (MO) diagram. Given that the four (4) sigma-ligand group orbitals (o-LGOS) symmetries are aig, big, and cu.

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Answer the following questions for square planar metal complexes ML4 (point group Dan):
1) determine the orbitals symmetries of the central metal atom and draw symmetry labelled molecular
orbital (MO) diagram. Given that the four (4) sigma-ligand group orbitals (o-LGOS) symmetries are
alg, big, and cu.
2) draw the MO diagrams to show the effect of pi-back bonding in the square planar metal complexes
[Pt(CN).] and [PtICLJ. Given that the eight (8) pi-ligand group orbitals (r-LGOS) symmetries are
a2g, bag, azu, bzu, Cg and e.
Transcribed Image Text:Answer the following questions for square planar metal complexes ML4 (point group Dan): 1) determine the orbitals symmetries of the central metal atom and draw symmetry labelled molecular orbital (MO) diagram. Given that the four (4) sigma-ligand group orbitals (o-LGOS) symmetries are alg, big, and cu. 2) draw the MO diagrams to show the effect of pi-back bonding in the square planar metal complexes [Pt(CN).] and [PtICLJ. Given that the eight (8) pi-ligand group orbitals (r-LGOS) symmetries are a2g, bag, azu, bzu, Cg and e.
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