3) The molecule [CuFaJK, has a unique structure (due to jahn-teller distortion) where it has an elongated z-axis in the octahedral structure which changes its point group from O, to Dan. Answer the following questions related to elongated structure of [CuFJK. a. The oxidation state of Cu: and F: b. Calculate the total number of electrons for (CuFo)*: c. Draw the MO diagram for sigma bonding only of [CuFe]K4 including the following i. Correct energy positions for each orbital ii. Symmetry labels including the type of bonding (i.e. t (non-bonding) for an octahedral structure) iii. Fill orbitals with the correct number of electrons

3) The molecule [CuFaJK, has a unique structure (due to jahn-teller distortion) where it has an elongated z-axis in the octahedral structure which changes its point group from O, to Dan. Answer the following questions related to elongated structure of [CuFJK. a. The oxidation state of Cu: and F: b. Calculate the total number of electrons for (CuFo)*: c. Draw the MO diagram for sigma bonding only of [CuFe]K4 including the following i. Correct energy positions for each orbital ii. Symmetry labels including the type of bonding (i.e. t (non-bonding) for an octahedral structure) iii. Fill orbitals with the correct number of electrons

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter6: Quantum Mechanics And Molecular Structure

Section: Chapter Questions

Problem 30P: The molecular ion HeH+ has an equilibrium bond length of 0.774 Å. Draw an electron correlation...

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Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.

Question

3)
The molecule [CUFJK, has a unique structure (due to jahn-teller distortion) where it has an
elongated z-axis in the octahedral structure which changes its point group from On to Dah. Answer the
following questions related to elongated structure of [CuFg]K4.
a. The oxidation state of Cu:
and F:
b. Calculate the total number of electrons for (CuFo)*:_
c. Draw the MO diagram for sigma bonding only of (CuF6]K4 including the following
i. Correct energy positions for each orbital
ii. Symmetry labels including the type of bonding (i.e. t25 (non-bonding) for
an octahedral structure)
iii. Fill orbitals with the correct number of electrons

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The molecule (CUFJK, has a unique structure (due to jahn-teller distortion) where it has an elongated z-axis in the octahedral structure which changes its point group from O, to Dah. Answer the following questions related to elongated structure of (CuFeJK. a. The oxidation state of Cu: and F: b. Calculate the total number of electrons for [CuFd]: C. Draw the MO diagram for sigma bonding only of (CuFa]Ka including the following i. Correct energy positions for each orbital ii. Symmetry labels including the type of bonding (i.e. the (non-bonding) for an octahedral structure) iii. Fill orbitals with the correct number of electrons
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