Consider the four sigma bonds of the square planar (PICP complex. If the molecule is on the xy plane and the colinear Cl-Pt-C bonds contain the C: C;" bisects the C-Pt-Cl bond angle: , cuts through the colinear Cl-Pt-a bonds: and bisects the C-Pt-CI bond angle: what is the character of the Cala) operation? Character table for De point group E 2C, c 20 2c", 25, 20, 20. linears, quadratic rotations Pey", A 1 1 -1 |-1||14 -1 B xy 200 2 0 200 R,.R,) (xz. yz) A A -1 E 2 -2 0 0 2 0 20 (x, y)

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Consider the four sigma bonds of the square planar [P:CI,? complex. If the molecule is on the xy plane and the
colinear Cl-Pt-CI bonds contain the C2: Cz" bisects the Cl-Pt-CI bond angle: , cuts through the colinear Cl-Pt-CI
bonds: and a bisects the Cl-Pt-CI bond angle; what is the character of the Calz) operation?
Character table for Da point group
E 2C4 (2) C, 20', 20";i 25, 20, 204
1111 1
-1 -111 1-1
-1 1 -1 11 -1
linears,
quadratic
rotations
A
R
x y?
-1
-1
-1
xy
2 00 20 2 00 (R,. R,) (xz. ya)
1111-1 -1 -1 -1
1-1 -1 -1-1 -111
-1 -1 1 -1 -1
I 11-11 -
0 202 0 0 (x. y)
E 2
A
Azu1
-1
B21
E 2
-1
-1
-2 0
O 2
04
---
Transcribed Image Text:Consider the four sigma bonds of the square planar [P:CI,? complex. If the molecule is on the xy plane and the colinear Cl-Pt-CI bonds contain the C2: Cz" bisects the Cl-Pt-CI bond angle: , cuts through the colinear Cl-Pt-CI bonds: and a bisects the Cl-Pt-CI bond angle; what is the character of the Calz) operation? Character table for Da point group E 2C4 (2) C, 20', 20";i 25, 20, 204 1111 1 -1 -111 1-1 -1 1 -1 11 -1 linears, quadratic rotations A R x y? -1 -1 -1 xy 2 00 20 2 00 (R,. R,) (xz. ya) 1111-1 -1 -1 -1 1-1 -1 -1-1 -111 -1 -1 1 -1 -1 I 11-11 - 0 202 0 0 (x. y) E 2 A Azu1 -1 B21 E 2 -1 -1 -2 0 O 2 04 ---
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