3. For trans [RuX₂(CO)₂L₂] complex, what are the irreducible representation for experimentally observed IRA, stretching bands?DanE C₂(z) C₂(x) C₂(x). i o(xy) o(xz) (yz)111ÁgBigB29BagAuB₁uB₂KВзи(A) Ag11111111-1- 111-1-11- 11- 1- 11-1(B) Blu-1I1PIRITTE1111111 -11-11-1www.Xhe111(C) B2u111- 11-11-1(D) B3u-111R₂R₂RxIyx², J², z²yzSH

The objective of this question is to explain the irreducible representation how a molecular…

3. For trans [RuX₂(CO)₂L₂] complex, what are the irreducible representation for experimentally observed IR A, stretching bands? D2h E C₂(3) C₂(y) C₂(x) i o(xy) o(xz) o(yz) Ág Big B29 Bag Au В 11 B₂x Взи CAVA 1 1 1 1 1 1 -1 -1 1 - 1 PIR 1 - 1 1 - 1 -1 1 - 1 -1 I 1 -1 -1 1 1 1 -1 1 1 1 1 -1 -1 1 1 (B₂ 1 (m) Bau 1 R₂ Ry R NAX x²,², z² xy XZ yz

3. For trans [RuX₂(CO)₂L₂] complex, what are the irreducible representation for experimentally observed IR A, stretching bands? D2h E C₂(3) C₂(y) C₂(x) i o(xy) o(xz) o(yz) Ág Big B29 Bag Au В 11 B₂x Взи CAVA 1 1 1 1 1 1 -1 -1 1 - 1 PIR 1 - 1 1 - 1 -1 1 - 1 -1 I 1 -1 -1 1 1 1 -1 1 1 1 1 -1 -1 1 1 (B₂ 1 (m) Bau 1 R₂ Ry R NAX x²,², z² xy XZ yz

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Related questions

Q: The symbol of the spectroscopic term and the number of electronic transitions for the [Ti(H2O)6]2+…

A: The electronic transitions are associated with the excitation of electrons UV and visible range.…

Q: Identify the general and specific types of isomerism for the following 2 species: NH3 NH3 Cl-Pt- OCN…

A: Given are two coordination compounds

Q: Square planar complexes are often asso with:

A: Square planar complexes are dsp2 hybridised .

Q: НО. OH CF3 Br Br Bpin Ac₂O, pyr, DMAP COOH N3-1-O cal Fe(OAc)2/ligand CN BnNH₂ Pd₂(dba)3 SPhos K3PO4…

Q: The_isomer of [Fe(NH3)3CI3] has C2y symmetry. mer fac

A: Welcome to bartleby!

Q: What would you expect the coordination sphere for the complex ion formed from Ni^2+ and…

A: In coordination chemistry, the first coordination sphere refers to the array of molecules and ions…

Q: Me3P-M ligand is a pi acceptor or pi donor?

A: A ligand can act as a pi donor or pi acceptor based on the fact that a pi donor ligand will have…

Q: Which of the three selection rules (spin, orbital, Laporte) are broken by the following transition?…

A: Spin selection rule: During the transition of electrons spin multiplicity should not change (ΔS =…

Q: Which of the following octahedral complex transition metal ions would have the same magnetic moment…

A: Given : ions

Q: What is the coordination of the cobalt ion in the compound: K[Co(ox)2CI(H2O)] ? А. 4-coordinate,…

A: Given-> K2[Co(ox)2Cl(H2O)]

Q: 3. Construct energy-level diagrams for both high- and low- spin situations for the dº electron…

A: High Spin Configuration: In the high spin configuration, the electrons occupy the higher energy…

Q: 4. Give an example of the following (where CN is coordination number) and include the point group:…

Q: What is the coordination number around the central metal atom in hexaaquachromium(III)…

A: The total number of donor atoms of the ligands attached to the central metal metal is called the…

Q: We have a mixture of 100 mL of Fe3+ solution (1.00 × 10–3 M) and 100 mL of A- ion solution (1.00 ×…

A: We have find out the Balance the equations and the concentrations of the remaining species.Also find…

Q: Draw the d orbital diagram for the following molecules/ions and calculate CFSE energy. a.…

Q: 3. Square planar Ir complexes have been widely studied in organometallic catalysis. Provided the…

Q: What is the LFSE for the [Co(bipy)3]Cl2 complex, knowing that $\Delta$o = 11300 cm-1 and P= 22500…

A: LFSE is the ligand field stabilization energy. For the given complex, Co is in +2 state. A strong…

Q: Which of the following complex has the highest effective magnetic moment ○ K₂MnO4 K₂MnCl₁ K.Mn(CN)…

A: In order to determine the effective magnetic moment, we first need to determine the oxidation state…

Q: b) Explain the trend in the IR stretching frequency, v(CO), for the metal carbonyl complexes below:…

A: Detailed explanation:-[Ti(CO)6]2−IR stretching frequency: 1748 cm⁻¹The titanium in [Ti(CO)6]2−…

Q: Give the systematic name for the following coordination compound: CI- .F Со

A: While naming any complex ion, the ligands are always named before the metal ion. If multiple ligands…

Q: A complex only absorbs light with an energy of 4.42x10-19 J. What color do we see for the complex?

Q: 13. Which of the following is more paramagne [Mn(NO₂)] or [Mn(H₂O)]³+ 14. Is the reaction O₂ + 4H +…

A: Answer-14 A reaction can only be spontaneous when Gibbs free energy change for it is negative and…

Q: a. the shape of its complex. b. the expected type of hybridization c. the number of coordination…

A: "Since there are multiple sub-parts in this question and it is not mentioned that which one has to…

Concept explainers

Atomic Structure

The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.

Shape of the D Orbital

Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.

Question

3. For trans [RuX₂(CO)₂L₂] complex, what are the irreducible representation for experimentally observed IR
A, stretching bands?
Dan
E C₂(z) C₂(x) C₂(x). i o(xy) o(xz) (yz)
1
1
1
Ág
Big
B29
Bag
Au
B₁u
B₂K
Взи
(A) Ag
1
1
1
1
1
1
1
1
-1
- 1
1
1
-1
-1
1
- 1
1
- 1
- 1
1
-1
(B) Blu
-1
I
1
PIRITTE
1
1
1
1
1
1
1 -1
1
-1
1
-1
www.
Xhe
1
1
1
(C) B2u
1
1
1
- 1
1
-1
1
-1
(D) B3u
-1
1
1
R₂
R₂
Rx
I
y
x², J², z²
yz
SH

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1: Introduction

VIEW

Step 2: Analysis

VIEW

Step 3: Symmetry elements

VIEW

Solution

VIEW

Step by step

Solved in 4 steps

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

INORGANIC CHEMISTRY
The symmetry of the metal d-orbitals that involve in sigma bond formation in octahedral complex compounds are 0128 eg eg * 128
See image below... What determines whether these are high spin or low spin or neither?
For the complex [V(H2O)6]2+, the spectroscopic term of the ground state is: Select one: a. 3P b. 5D c. 4F d. 4P e. 4S
What is the spin-only magnetic moment for the [NiCl4]Cl2 complex?
If you mix Cu2+ with , a. NaCl, b. NaNO2, c. H2O , arrange the solutions based on their absorption from highest frequency to lowest frequency? A) a, b, c B) a, c, b C) b, c, a D) c, b, a E) All solutions will absorb at the same wavelength, only the amount of absorption changes based on the ligand strength
2. Short questions, all-or-nothing. There may be more than one answer per question. axial 3- CN NC Ni CN CN equatorial NC а. For the square base pyramidal complex [Ni(CN)s]3 shown above, of Cav point group, consider the rotation axes: 2C4 and C2. If the axial CN ligand was substituted by CO, forming [Ni(CO)(CN)4]?, maintaining the square pyramidal geometry, which symmetry elements would be retained: i. Both C4 and C2. ii. Only the C2. iii. Only the C4. iv. None of the above b. Looking at the symmetry planes: 20v, 20d; what symmetry elements would be retained if the Co substitution would occur on an equatorial CN ligand (forming again [Ni(CO)(CN)4]?) instead? The dihedral planes in this case is the mirror plane that bisects the square planar bonds. i. All ov ii. All od iii. At least 1 od iv. At least 1 oy