Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
![**Systematic Naming of Coordination Compounds**
**Coordination Compound:**
In the given diagram, a coordination compound is illustrated with the chemical structure:
- Central atom: Co (Cobalt)
- Ligands: Cl (Chlorine) and F (Fluorine)
The structure forms an octahedral arrangement around the central cobalt atom with chloride and fluoride ions.
**Objective:**
Provide the systematic name for the coordination compound.
**Naming Components:**
1. **Prefixes**: Used to indicate the number of each type of ligand.
- bis, tris, tetrakis, etc.
2. **Ligand Names**:
- chloro for Cl
- fluoro for F
3. **Stereochemistry**:
- Use prefixes like cis-, trans-, fac-, mer- to denote arrangement.
4. **Oxidation State** of Metal (in Roman numerals):
- For cobalt, possibilities like (II), (III) based on the compound's charge.
5. **Metal Name**:
- For neutral/positive: cobalt
- For negative: cobaltate
**Word Bank for Naming**:
- Parentheses and ion indications
- Metal oxidation states: (I) (II) (III) (IV) (V)
- Stereochemical descriptors: mer-, cis-, fac-, trans-
- Numerical prefixes: di, tri, tetra
- Ligand names: chloro, fluoro, etc.
- Metal names: cobalt, cobaltate
**Example Steps for Naming**:
- Identify ligands and count.
- Apply numerical prefixes to ligand names.
- Use appropriate stereochemistry prefixes.
- Determine the oxidation state for cobalt.
- Assemble the name in the order: [Stereochemistry][Ligands][Metal][Oxidation State].
Ensure the final systematic name adheres to IUPAC nomenclature guidelines for coordination compounds.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fc8594442-3c1c-4b58-8439-4303aac47a4e%2F9ea7716e-bc28-41df-b631-34a6105daace%2Fy1ex9x1_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Systematic Naming of Coordination Compounds**
**Coordination Compound:**
In the given diagram, a coordination compound is illustrated with the chemical structure:
- Central atom: Co (Cobalt)
- Ligands: Cl (Chlorine) and F (Fluorine)
The structure forms an octahedral arrangement around the central cobalt atom with chloride and fluoride ions.
**Objective:**
Provide the systematic name for the coordination compound.
**Naming Components:**
1. **Prefixes**: Used to indicate the number of each type of ligand.
- bis, tris, tetrakis, etc.
2. **Ligand Names**:
- chloro for Cl
- fluoro for F
3. **Stereochemistry**:
- Use prefixes like cis-, trans-, fac-, mer- to denote arrangement.
4. **Oxidation State** of Metal (in Roman numerals):
- For cobalt, possibilities like (II), (III) based on the compound's charge.
5. **Metal Name**:
- For neutral/positive: cobalt
- For negative: cobaltate
**Word Bank for Naming**:
- Parentheses and ion indications
- Metal oxidation states: (I) (II) (III) (IV) (V)
- Stereochemical descriptors: mer-, cis-, fac-, trans-
- Numerical prefixes: di, tri, tetra
- Ligand names: chloro, fluoro, etc.
- Metal names: cobalt, cobaltate
**Example Steps for Naming**:
- Identify ligands and count.
- Apply numerical prefixes to ligand names.
- Use appropriate stereochemistry prefixes.
- Determine the oxidation state for cobalt.
- Assemble the name in the order: [Stereochemistry][Ligands][Metal][Oxidation State].
Ensure the final systematic name adheres to IUPAC nomenclature guidelines for coordination compounds.
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