Consider two fixed-volume systems A and B, in thermal equilibrium and that can exchange two different types of particles (say type 1 and type 2). Given that equilibrium is a state of highest multiplicity, show that in order for A and B to be in equilibrium, then systems A and B must have equal chemical potential in each type of particles that they can exchange.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Consider two fixed-volume
systems A and B, in thermal
equilibrium and that can
exchange two different types of
particles (say type 1 and type 2).
Given that equilibrium is a state of
highest multiplicity, show that in
order for A and B to be in
equilibrium, then systems A and B
must have equal chemical
potential in each type of particles
that they can exchange.
Transcribed Image Text:Consider two fixed-volume systems A and B, in thermal equilibrium and that can exchange two different types of particles (say type 1 and type 2). Given that equilibrium is a state of highest multiplicity, show that in order for A and B to be in equilibrium, then systems A and B must have equal chemical potential in each type of particles that they can exchange.
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