Consider the following elementary reaction mechanism where both the forward and reverse reactions are important: kf1 CO+O₂ CO₂ +0 kr1 O+H₂O OH+OH kf2 kr2 Kf3 CO+OHCO₂ + H k,3 2 kƒ4 H+0₂ ⇒OH+O kr 4 1. Write all chemical rate differential equations that are needed to determine the chemical evolution of the system. Write all initial conditions that are needed to determine the chemical evolution of the system. 2. 3. Is this system of rate differential equations sufficient to solve for the evolution of compositions of each chemical species? Explain, including a discussion of what else might be needed.

Chemistry
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Chapter1: Chemical Foundations
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Consider the following elementary reaction mechanism where both the forward and reverse reactions are
important:
kf1
CO+O₂ CO₂ +0
2
kr1
O+H₂O OH+OH
kƒ2
kr2
kƒ3
CO+OH=CO,+H
k₁.3
kf4
H+0,⇒OH+O
kr 4
1. Write all chemical rate differential equations that are needed to determine the chemical evolution of
the system.
2. Write all initial conditions that are needed to determine the chemical evolution of the system.
3. Is this system of rate differential equations sufficient to solve for the evolution of compositions of each
chemical species? Explain, including a discussion of what else might be needed.
Transcribed Image Text:Consider the following elementary reaction mechanism where both the forward and reverse reactions are important: kf1 CO+O₂ CO₂ +0 2 kr1 O+H₂O OH+OH kƒ2 kr2 kƒ3 CO+OH=CO,+H k₁.3 kf4 H+0,⇒OH+O kr 4 1. Write all chemical rate differential equations that are needed to determine the chemical evolution of the system. 2. Write all initial conditions that are needed to determine the chemical evolution of the system. 3. Is this system of rate differential equations sufficient to solve for the evolution of compositions of each chemical species? Explain, including a discussion of what else might be needed.
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