Consider the following elementary mechanism: k₁ A2 (g)= = 2A (g) k-1 k₂ A + B (g) P (g) For the reversible reaction above, we assume the pre-equilibrium approximation. Write down the expression for the pre-equilibrium approximation. Using the pre-equilibrium approximation, derive the predicted rate law expression for this mechanism. The rate law should depend upon A2 and B but not P.

Consider the following elementary mechanism: k₁ A2 (g)= = 2A (g) k-1 k₂ A + B (g) P (g) For the reversible reaction above, we assume the pre-equilibrium approximation. Write down the expression for the pre-equilibrium approximation. Using the pre-equilibrium approximation, derive the predicted rate law expression for this mechanism. The rate law should depend upon A2 and B but not P.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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