Consider a particle in a one-dimensional rigid box of length a. Recall that a rigid box has U (x) = 00 for a <0 and a> a, and U(2) = 0 for 0 < a < a. Suppose the particle is in the second excited state (two states above the ground state). (The next 2 problems below pertain to this information.)

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### Most Probable Positions in the Second Excited State of a One Dimensional Rigid Box

In this educational section, we will discuss the concept of the most probable positions \( x_{\text{mp}} \) of a particle in the second excited state of a one-dimensional rigid box. 

For detailed formulas and mathematical background, please refer to the provided document:
[Formulas.pdf](#)

#### Explanation:
In quantum mechanics, when a particle is confined in a one-dimensional rigid box (also known as an infinite potential well), the energy levels and corresponding wave functions are quantized. For a box of length \( L \), the wave function for the \( n \)-th state is given by:

\[
\psi_n(x) = \sqrt{\frac{2}{L}} \sin{\left( \frac{n \pi x}{L} \right)},
\]

where \( n \) is a positive integer representing the quantum number of the state.

In the second excited state (\( n = 3 \)), the wave function becomes:

\[
\psi_3(x) = \sqrt{\frac{2}{L}} \sin{\left( \frac{3 \pi x}{L} \right)}.
\]

The probability density function, which determines the probability of finding the particle at a position \( x \), is given by:

\[
|\psi_3(x)|^2 = \left( \sqrt{\frac{2}{L}} \sin{\left( \frac{3 \pi x}{L} \right)} \right)^2 = \frac{2}{L} \sin^2{\left( \frac{3 \pi x}{L} \right)}.
\]

Using this probability density function, we can deduce the positions where the particle is most likely to be found, known as the most probable positions \( x_{\text{mp}} \).

#### Key Points:
- The particle in the second excited state of a one-dimensional rigid box has quantized energy levels and wave functions.
- The wave function for the second excited state (\( n = 3 \)) is \( \psi_3(x) \).
- The probability density function is \( |\psi_3(x)|^2 = \frac{2}{L} \sin^2{\left( \frac{3 \pi x}{L} \right)} \).

To find the most probable positions, we seek the
Transcribed Image Text:### Most Probable Positions in the Second Excited State of a One Dimensional Rigid Box In this educational section, we will discuss the concept of the most probable positions \( x_{\text{mp}} \) of a particle in the second excited state of a one-dimensional rigid box. For detailed formulas and mathematical background, please refer to the provided document: [Formulas.pdf](#) #### Explanation: In quantum mechanics, when a particle is confined in a one-dimensional rigid box (also known as an infinite potential well), the energy levels and corresponding wave functions are quantized. For a box of length \( L \), the wave function for the \( n \)-th state is given by: \[ \psi_n(x) = \sqrt{\frac{2}{L}} \sin{\left( \frac{n \pi x}{L} \right)}, \] where \( n \) is a positive integer representing the quantum number of the state. In the second excited state (\( n = 3 \)), the wave function becomes: \[ \psi_3(x) = \sqrt{\frac{2}{L}} \sin{\left( \frac{3 \pi x}{L} \right)}. \] The probability density function, which determines the probability of finding the particle at a position \( x \), is given by: \[ |\psi_3(x)|^2 = \left( \sqrt{\frac{2}{L}} \sin{\left( \frac{3 \pi x}{L} \right)} \right)^2 = \frac{2}{L} \sin^2{\left( \frac{3 \pi x}{L} \right)}. \] Using this probability density function, we can deduce the positions where the particle is most likely to be found, known as the most probable positions \( x_{\text{mp}} \). #### Key Points: - The particle in the second excited state of a one-dimensional rigid box has quantized energy levels and wave functions. - The wave function for the second excited state (\( n = 3 \)) is \( \psi_3(x) \). - The probability density function is \( |\psi_3(x)|^2 = \frac{2}{L} \sin^2{\left( \frac{3 \pi x}{L} \right)} \). To find the most probable positions, we seek the
**Quantum Mechanics: Particle in a 1D Rigid Box**

Consider a particle in a one-dimensional rigid box of length \( a \). Recall that a rigid box has \( U(x) = \infty \) for \( x < 0 \) and \( x > a \), and \( U(x) = 0 \) for \( 0 \le x \le a \). Suppose the particle is in the second excited state (two states above the ground state).

(The next 2 problems below pertain to this information.)

**Resources**
[Formulas.pdf (Click here-->)
Transcribed Image Text:**Quantum Mechanics: Particle in a 1D Rigid Box** Consider a particle in a one-dimensional rigid box of length \( a \). Recall that a rigid box has \( U(x) = \infty \) for \( x < 0 \) and \( x > a \), and \( U(x) = 0 \) for \( 0 \le x \le a \). Suppose the particle is in the second excited state (two states above the ground state). (The next 2 problems below pertain to this information.) **Resources** [Formulas.pdf (Click here-->)
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