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COCH3 -- a) N: OH CO2CH3 CH3 CH2PH N. b) (CH3)½N-C(OCH3)2 .N. 180°C CH2CN(CH3)2 но CH2CH3 CH,CH3 OCCH3 O 1) 2 LIN'Pr2 (LDA) os'Bu(C OCCH3 2) 2 'Bu(CH32SICI c) (CH3)2 BuSio 3) 60°C

COCH3 -- a) N: OH CO2CH3 CH3 CH2PH N. b) (CH3)½N-C(OCH3)2 .N. 180°C CH2CN(CH3)2 но CH2CH3 CH,CH3 OCCH3 O 1) 2 LIN'Pr2 (LDA) os'Bu(C OCCH3 2) 2 'Bu(CH32SICI c) (CH3)2 BuSio 3) 60°C

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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4. Write a mechanism for each of the following reactions. Use the mechanistic arrow convention to show electron flow for ionic (polar) steps and for pericyclic steps and include the structure of all important reaction intermediates.
Transcribed Image Text:4. Write a mechanism for each of the following reactions. Use the mechanistic arrow convention to show electron flow for ionic (polar) steps and for pericyclic steps and include the structure of all important reaction intermediates.
CO2CH3 COCH3 a) OH CO2CH3 CH3 (CH3)2N-C(OCH3)2 CH2PH N. N. b) 180°C CH2CN(CH3)2 но CH2CH3 CH,CH3 OCCH3 1) 2 LİN'Pr2 (LDA) Osi'Bu(CH3)2 OCCH3 2) 2 'Bu(CH32SICI c) (CH3)2 BuSiO 3) 60°C O
Transcribed Image Text:CO2CH3 COCH3 a) OH CO2CH3 CH3 (CH3)2N-C(OCH3)2 CH2PH N. N. b) 180°C CH2CN(CH3)2 но CH2CH3 CH,CH3 OCCH3 1) 2 LİN'Pr2 (LDA) Osi'Bu(CH3)2 OCCH3 2) 2 'Bu(CH32SICI c) (CH3)2 BuSiO 3) 60°C O
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