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4. For the following reactions tell which should have kH/kD values greater than 1.5 for isotopic substitution at the starred hydrogens: (a) (b) (c) CH₂ 6 H₂ CH₂ CH NO₂ C CI EtyN OH (CH₂CH-CH- CH₂CH₂ OSO₂Ar % H,C EICH NIFT * -CH-C=O HNEL, CI- NO CH₂ 1 + H₂O {CH}'=CH-CH,CH, + ArSO H

4. For the following reactions tell which should have kH/kD values greater than 1.5 for isotopic substitution at the starred hydrogens: (a) (b) (c) CH₂ 6 H₂ CH₂ CH NO₂ C CI EtyN OH (CH₂CH-CH- CH₂CH₂ OSO₂Ar % H,C EICH NIFT * -CH-C=O HNEL, CI- NO CH₂ 1 + H₂O {CH}'=CH-CH,CH, + ArSO H

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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4. For the following reactions tell which should have kH/kD values greater than 1.5 for isotopic substitution at the starred hydrogens: (a) -CH=C=0₁ HNEI, CI (b) (c) CH₂ H₂ CH₂ CH NO₂ C CI Et N OH (CH₂ CH CH – CH₂CH₂ OSO₂Ar fo H,C NO EICH NIFT CH₂ + H₂O (CH)!=CH-CH,CH, + ArSO,H
Transcribed Image Text:4. For the following reactions tell which should have kH/kD values greater than 1.5 for isotopic substitution at the starred hydrogens: (a) -CH=C=0₁ HNEI, CI (b) (c) CH₂ H₂ CH₂ CH NO₂ C CI Et N OH (CH₂ CH CH – CH₂CH₂ OSO₂Ar fo H,C NO EICH NIFT CH₂ + H₂O (CH)!=CH-CH,CH, + ArSO,H
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