Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![What structure is identical to this molecule?
(A)
H3C
(A)
CH3
OH
H3C
(B)
(A)
(B)
H₂C
PQ-14. Which compound has the IUPAC name trans-1-chloro-3-ethylcyclohexane?
CI
CI
(A) I and II
(B)
CH3
OH
PQ-13. What best describes the most stable conformation of trans-1-isopropyl-3-methylcyclohexane?
(A) The isopropyl group is equatorial, and the methyl group is axial.
(B) The isopropyl group is axial, and the methyl group is equatorial.
(C) Both the isopropyl and methyl groups are equatorial.
(D) Both the isopropyl and methyl groups are axial.
PQ-18. Which is/are optically inactive?
H
CH3
H
PQ-16. Which value is closest to the internal C-C-C bond angle in cyclohexane?
(A) 90⁰
(B) 100°
(C) 110⁰
OH
к он
CH3
(C)
CH3
I
(B) II only
H.
(C)
HO
50
H3C
PQ-15. What factor is responsible for a greater heat of combustion per CH₂ for cyclopropane than the heat of
combustion per CH₂ for cyclohexane.
(A) Cyclohexane has a different hydrogen-to-carbon atom ratio than cyclopropane.
(B) Cyclohexane has greater ring strain than cyclopropane.
(C) Cyclopropane is a strained ring relative to cyclohexane.
(D) Cyclohexane has more carbon atoms than cyclopropane.
(C)
CH3
HO
CH3
PQ-17. Which molecules would have the highest heat of combustion, or release most energy when burned to
produce CO₂ and H₂O?
OH
OH
H
CH3
CI
CH3
II
(C) III only
CH3
(D)
III
H-OH
H
H - OH
CH 3
III
H
(D)
CH3
H3C
(D)
CH₂CH3
H3C
(D) 120°
CH 3
OH
(D) II and III
CI](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F94cb56ce-f9a7-474a-b997-77a13b6dc73a%2F3fd77b67-74a7-478d-91d9-977efb02dae1%2Fyy7mi_processed.jpeg&w=3840&q=75)
Transcribed Image Text:What structure is identical to this molecule?
(A)
H3C
(A)
CH3
OH
H3C
(B)
(A)
(B)
H₂C
PQ-14. Which compound has the IUPAC name trans-1-chloro-3-ethylcyclohexane?
CI
CI
(A) I and II
(B)
CH3
OH
PQ-13. What best describes the most stable conformation of trans-1-isopropyl-3-methylcyclohexane?
(A) The isopropyl group is equatorial, and the methyl group is axial.
(B) The isopropyl group is axial, and the methyl group is equatorial.
(C) Both the isopropyl and methyl groups are equatorial.
(D) Both the isopropyl and methyl groups are axial.
PQ-18. Which is/are optically inactive?
H
CH3
H
PQ-16. Which value is closest to the internal C-C-C bond angle in cyclohexane?
(A) 90⁰
(B) 100°
(C) 110⁰
OH
к он
CH3
(C)
CH3
I
(B) II only
H.
(C)
HO
50
H3C
PQ-15. What factor is responsible for a greater heat of combustion per CH₂ for cyclopropane than the heat of
combustion per CH₂ for cyclohexane.
(A) Cyclohexane has a different hydrogen-to-carbon atom ratio than cyclopropane.
(B) Cyclohexane has greater ring strain than cyclopropane.
(C) Cyclopropane is a strained ring relative to cyclohexane.
(D) Cyclohexane has more carbon atoms than cyclopropane.
(C)
CH3
HO
CH3
PQ-17. Which molecules would have the highest heat of combustion, or release most energy when burned to
produce CO₂ and H₂O?
OH
OH
H
CH3
CI
CH3
II
(C) III only
CH3
(D)
III
H-OH
H
H - OH
CH 3
III
H
(D)
CH3
H3C
(D)
CH₂CH3
H3C
(D) 120°
CH 3
OH
(D) II and III
CI
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