3. Assign E or Z stereochemistry to the following alkenes: (a) НОСH2 CH3 (b) HO2C H C=C C=C H3C H CI OCH3 NC (d) CH3O2C CH=CH2 CH3 c=c (c) C=C CH3CH2 CH2OH HO2C CH2CH3

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Chapter1: Chemical Foundations
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3.
Assign E or Z stereochemistry to the following alkenes:
(a) НОСН2
CH3
(b) HO2C
H
C=C
C=C
H3C
CI
OCH3
(c)
NC
CH3
(d) CH3O2C
CH=CH2
C=C
C=C
CH3CH2
CH2OH
HO2C
CH2CH3
4.
Classify the following reactions as additions, eliminations, substitutions, or
rearrangements:
(а) CН3Br + KоН — СH3ОН + KBr
(b) CH3CH2C1 + NaOH →
(c) H2C=CH2 + H2
H2C=CH2 + NaCl
CH3CH3
5.
Which of the following are most likely to behave as electrophiles, and which as
nucleophiles? Explain.
(a) NH4+
(b) C=N-
(c) Br+
(d) CH3NΗ,
(е) Н—С—С-—н
Transcribed Image Text:3. Assign E or Z stereochemistry to the following alkenes: (a) НОСН2 CH3 (b) HO2C H C=C C=C H3C CI OCH3 (c) NC CH3 (d) CH3O2C CH=CH2 C=C C=C CH3CH2 CH2OH HO2C CH2CH3 4. Classify the following reactions as additions, eliminations, substitutions, or rearrangements: (а) CН3Br + KоН — СH3ОН + KBr (b) CH3CH2C1 + NaOH → (c) H2C=CH2 + H2 H2C=CH2 + NaCl CH3CH3 5. Which of the following are most likely to behave as electrophiles, and which as nucleophiles? Explain. (a) NH4+ (b) C=N- (c) Br+ (d) CH3NΗ, (е) Н—С—С-—н
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