9. Shown here is variable-temperature 'H NMR data of the germanium complex show below. At low temperature the data shows a peak at roughly 3.2ppm and two peaks that overlap at roughly 6.5ppm (protons on methyl groups not shown). At high temperature, we now observe a single peak. How do you account for this change in the 'H NMR data with temperature? What is the mechanism called? H-NMR H H. H "GeMez 346K 317K 304K 275K 256K 238K 216K 8'HVppm
Catalysis and Enzymatic Reactions
Catalysis is the kind of chemical reaction in which the rate (speed) of a reaction is enhanced by the catalyst which is not consumed during the process of reaction and afterward it is removed when the catalyst is not used to make up the impurity in the product. The enzymatic reaction is the reaction that is catalyzed via enzymes.
Lock And Key Model
The lock-and-key model is used to describe the catalytic enzyme activity, based on the interaction between enzyme and substrate. This model considers the lock as an enzyme and the key as a substrate to explain this model. The concept of how a unique distinct key only can have the access to open a particular lock resembles how the specific substrate can only fit into the particular active site of the enzyme. This is significant in understanding the intermolecular interaction between proteins and plays a vital role in drug interaction.
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