13.36 How many signals would you expect each of the following molecules to have in its 'H and 13C spectra? (a) H3C (e) O CH3CH3 CH3 (b) CH3 CH3 H3c CH3 (d) Hof 9 CHC-C-OCH3 (e) CH3 „CH3 CH3 H3C H3C

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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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13.36 How many signals would you expect each of the following molecules to have
in its 'H and 13C spectra?
(c) O
CH3CH3
(a) H3C
CH3
(b)
CH3
c=C
-CH3
H3C
CH3
CH3
(f)
„CH3
(e)
(d) H3C 0
CH3
CH3C-C-OCH3
H3C
Transcribed Image Text:13.36 How many signals would you expect each of the following molecules to have in its 'H and 13C spectra? (c) O CH3CH3 (a) H3C CH3 (b) CH3 c=C -CH3 H3C CH3 CH3 (f) „CH3 (e) (d) H3C 0 CH3 CH3C-C-OCH3 H3C
13.45 Propose structures for the two compounds whose 'H NMR spectra are shown.
(a) C4H9B1
Chem. Rel.
alle
shift
area
1.05
6.00
1.97
1.00
3.31
2.00
TMS
O ppm
10
8.
7
6
3
2
Chemical shift (6)
(b) C4H§C12
Chem. Rel.
shift
area
1.56
3.00
2.13
2.00
3.72
2.00
4.25
1.00
TMS
10
9.
8.
7
6
4
3
2 1
O ppm
Chemical shift (8)
Intensity
Intensity
Transcribed Image Text:13.45 Propose structures for the two compounds whose 'H NMR spectra are shown. (a) C4H9B1 Chem. Rel. alle shift area 1.05 6.00 1.97 1.00 3.31 2.00 TMS O ppm 10 8. 7 6 3 2 Chemical shift (6) (b) C4H§C12 Chem. Rel. shift area 1.56 3.00 2.13 2.00 3.72 2.00 4.25 1.00 TMS 10 9. 8. 7 6 4 3 2 1 O ppm Chemical shift (8) Intensity Intensity
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