Chem 201 Chapter 11 Worksheet1) Draw the MO diagram, calculate the bond order, and identify if the molecule is paramagnetic ordiamagnetic AND stable or not for the following: Liz, Be2, B2, C2, N2, O2, F2, Nez, Liz, Oz", Nez, Hz.

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Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Label the following molecular orbitals as σ or π orbitals and briefly explain. Be sure indicate the subscript (g or u) and superscript (with or without *), but you do not need to specify the number before σ or π.
Identify the molecular orbitals for cyclopropenyl. Select all that apply. 0₂ O π3* Oπ₂* □ π* 03 04 Oπ1 antibonding antibonding antibonding 4* antibonding
Question 5 of 22 A bond order of zero indicates that a species is unstable. Using MO diagrams, determine which of these diatomic species would have a bond order of zero. A) Ne,* B) C,* C) Cl,2- D) 0,- E) F2
Use the molecular orbital theory to determine the ground state electron configuration of F, and F. Molecule Ground state electron configuration [2] 4 4 (T2p 2 2 F, (01s) (01,*) 02) (02,*) (02) 2 (02) 2 2 4 F 2 (01s) (025) (#2p) (T2P Answer Bank 3 4 Then, use the molecular orbital theory to determine the bond order and magnetism of the molecules. F, bond order: F bond order: F, is O diamagnetic. O paramagnetic. 防is O diamagnetic, O paramagnetic. 2.
The atomic orbital, AO, contributions of penta-1,3-dienyl cation (shown to the right) are drawn in random order below. Using the A-E labels: (a) match the AO contributor to the MO energy diagram levels, (b) next to the MO diagram levels, identify each π MO as either bonding, nonbonding, or antibonding, (c) populate the T electrons in the appropriate MO energy levels, and (d) label the HOMO and the LUMO. 8 8 8 8 A (11 o* MOs) |||| (11 g Mos) B с D E
3. According to MO theory, which molecule or ion shown below has the highest bond order? Highest bond energy? Shortest bond strength? O2, C2-, O2^2- Draw MO energy diagrams for each of the species above and show your calculation or bond order. Also predict the magnetic properties in each case. Thank you very much.
about this FOLLOW-UP PROBLEM 11.4 Using MO Theory to Explain Bond Properties Enter your search term Determine the bond orders for the following species: Cl,2-, Cl2, Cl2, Cl2+, Cl,2+. Cl 2- Cl, Cl2 Cl2+ Cl,2+ bond order List the species in order of increasing bond energy and in order of increasing bond length. (If the species is unstable, consider the bond energy infinitely small and the bond length infinitely long. ) O Cl,2- O C2- O Cl,2- O Cl,2- Cl2 O Cl, O Cl2- Cl2 bond O C2 O l2 O C2 O Cl2 O C2 HINTS energy O Ch+ Getting Started I'm Stuck Cl, O Cl * O c1,2+ O Cl, 2+ O Cl,2+ O Cl,2+ O C, O Cl,²- O Cl,2 Cl,2- O Cl,2- O Cl,- O C), O C)- O Clz O Cl, bond length O C2 O Cl2 O C2 O C2 O Cl,+ O Cl, 2+ O Cl2+ O Cl + O Cl2+ O Cl2+ O C,2+ O C,2+ O cl, 2+ O Cl, 2+ O O
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Using a group theoretical approach, generate the MO diagrams for silane, SiH4. Be sure that your diagram is fully-labeled with MO assignments, is properly scaled in energy space, and provide a sketch of the MO. Determine the bond order for the silane molecule, and for the Si-H bond.
Use the template below to construct a MO diagram for the CN* molecule and use it to answer the following questions. In the completed diagram for CN*, the number of electrons in bonding orbitals is: in antibonding orbitals is: What is the bond order? If a fraction is needed, use a decimal number. CN* is Molecular orbitals Atomic orbitals (Atom A) Atomic orbitals (Atom B) 2p Encrgy
Using the appropriate MO diagram determine the bond orders for: a) F22+ b) F2-

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Chem 201 Chapter 11 Worksheet 1) Draw the MO diagram, calculate the bond order, and identify if the molecule is paramagnetic or diamagnetic AND stable or not for the following: Liz, Be2, B2, C2, N2, O2, F2, Nez, Liz, Oz", Nez, Hz.