Below is the MO diagrams for the diatomic molecule AB'. Which of the following will have the shorted AB bond length *2p 2p 2p 2s 2s 25 Select one: AB AB2- AB" АВ AB* and AB each have the same bond oder.
Below is the MO diagrams for the diatomic molecule AB'. Which of the following will have the shorted AB bond length *2p 2p 2p 2s 2s 25 Select one: AB AB2- AB" АВ AB* and AB each have the same bond oder.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Below is the MO (Molecular Orbital) diagram for the diatomic molecule AB. The question asks which of the given options will result in the shortest AB bond length.
### Molecular Orbital Diagram Explanation:
- **Energy Levels:**
- The diagram shows energy levels for atomic orbitals and molecular orbitals.
- Energy increases as you move up the diagram.
- **Atomic Orbitals:**
- Left and right sides represent the atomic orbitals of atoms A and B, specifically the 2s and 2p orbitals.
- **Molecular Orbitals:**
- Center portion shows the formation of molecular orbitals.
- Levels are labeled from bottom to top: σ(2s), σ*(2s), σ(2p), π(2p), π*(2p), and σ*(2p).
- **Electrons:**
- Red arrows inside each molecular orbital indicate the electrons occupying them.
### Molecular Orbital Electron Configuration:
- **σ(2s)**: Filled molecular orbital with 2 electrons.
- **σ*(2s)**: Antibonding molecular orbital with 2 electrons.
- **σ(2p)**: Bonding molecular orbital with 2 electrons.
- **π(2p)**: Bonding molecular orbitals (degenerate) with 4 electrons.
- **π*(2p)**: Antibonding molecular orbitals (degenerate) with 2 electrons.
- **σ*(2p)**: Empty antibonding molecular orbital.
### Options for Selection:
- AB
- AB²⁻
- AB⁺
- AB⁻ and AB⁺ each have the same bond order.
**Note:** Students are expected to determine the bond order for each option and understand how it correlates to bond length. Higher bond order generally indicates shorter bond length.
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