1) identify homo and lumo 2) suppose this molecule would have an extra electron .where would you put this extra electron in the atomic and molecular orbital above?

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1)

identify homo and lumo

2)

suppose this molecule would have an extra electron .where would you put this extra electron in the atomic and molecular orbital above?

This image depicts a molecular orbital (MO) diagram illustrating the electronic interactions between two atoms, Atom A and Atom B, as they form molecular orbitals.

**Description:**

1. **Atomic Orbitals (AO):**
   - On the left and right sides, there are atomic orbitals for Atom A and Atom B, respectively.
   - The 1s, 2s, and 2p orbitals are shown with electrons represented by arrows indicating their spins.

2. **Molecular Orbitals (MO):**
   - In the center is the molecular orbital configuration resulting from the combination of atomic orbitals.
   - The energy levels of the molecular orbitals increase upwards in the diagram.

3. **MO Energy Levels and Labels:**
   - The molecular orbitals are labeled as σ and π for bonding interactions, and π* and σ* for antibonding interactions.
   - From the bottom to top, the MO labels are: σ(1s), σ*(1s), σ(2s), σ*(2s), σ(2px), π(2py), π(2pz), π*(2py), π*(2pz), and σ*(2px).
   - The diagram is symmetric, reflecting the interaction of similar orbitals from both atoms.

4. **Electron Configuration:**
   - Electrons are filled in the molecular orbitals from lower to higher energy levels, following Hund’s rule and the Pauli exclusion principle.
   - Bonding MOs are filled first, followed by antibonding MOs if electrons remain.

5. **Energy Axis (E):**
   - The vertical arrow labeled "E" indicates increasing energy from bottom to top.

This MO diagram helps visualize bonding and antibonding interactions, crucial for understanding molecular stability and properties.
Transcribed Image Text:This image depicts a molecular orbital (MO) diagram illustrating the electronic interactions between two atoms, Atom A and Atom B, as they form molecular orbitals. **Description:** 1. **Atomic Orbitals (AO):** - On the left and right sides, there are atomic orbitals for Atom A and Atom B, respectively. - The 1s, 2s, and 2p orbitals are shown with electrons represented by arrows indicating their spins. 2. **Molecular Orbitals (MO):** - In the center is the molecular orbital configuration resulting from the combination of atomic orbitals. - The energy levels of the molecular orbitals increase upwards in the diagram. 3. **MO Energy Levels and Labels:** - The molecular orbitals are labeled as σ and π for bonding interactions, and π* and σ* for antibonding interactions. - From the bottom to top, the MO labels are: σ(1s), σ*(1s), σ(2s), σ*(2s), σ(2px), π(2py), π(2pz), π*(2py), π*(2pz), and σ*(2px). - The diagram is symmetric, reflecting the interaction of similar orbitals from both atoms. 4. **Electron Configuration:** - Electrons are filled in the molecular orbitals from lower to higher energy levels, following Hund’s rule and the Pauli exclusion principle. - Bonding MOs are filled first, followed by antibonding MOs if electrons remain. 5. **Energy Axis (E):** - The vertical arrow labeled "E" indicates increasing energy from bottom to top. This MO diagram helps visualize bonding and antibonding interactions, crucial for understanding molecular stability and properties.
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