1) Prepare a molecular orbital energy-level diagram for BrO [sp mixing is not significant in BrO] Orbital potential energies: Br: 4s -24.37 eV, 4p -12.49 eV; O: 2s -32.38 eV, 2p: -15.85 eV 2) Sketch the molecular orbital pictures (schematic representations) for the HOMO and LUMO in your MO diagram. 3) Hypobromite (BrO) is the bromine compound analogous to hypochlorites found in common bleaches, and in immune cells. In many ways, hypobromite functions in the same manner as hypochlorite, and is also used as a germicide and antiparasitic in both industrial applications, and in the immune system. For example, BrO can oxidize sulfhydryl groups in proteins. Which molecular orbital(s) of BrO would you predict to interact most strongly with the sulfhydryl groups in the protein to oxidize them? Explain.
1) Prepare a molecular orbital energy-level diagram for BrO [sp mixing is not significant in BrO] Orbital potential energies: Br: 4s -24.37 eV, 4p -12.49 eV; O: 2s -32.38 eV, 2p: -15.85 eV 2) Sketch the molecular orbital pictures (schematic representations) for the HOMO and LUMO in your MO diagram. 3) Hypobromite (BrO) is the bromine compound analogous to hypochlorites found in common bleaches, and in immune cells. In many ways, hypobromite functions in the same manner as hypochlorite, and is also used as a germicide and antiparasitic in both industrial applications, and in the immune system. For example, BrO can oxidize sulfhydryl groups in proteins. Which molecular orbital(s) of BrO would you predict to interact most strongly with the sulfhydryl groups in the protein to oxidize them? Explain.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![1) Prepare a molecular orbital energy-level diagram for BrO [sp mixing is not significant in BrO]
Orbital potential energies: Br: 4s -24.37 eV, 4p -12.49 eV; O: 2s -32.38 eV, 2p: -15.85 eV
2) Sketch the molecular orbital pictures (schematic representations) for the HOMO and LUMO in your
MO diagram.
3) Hypobromite (BrO) is the bromine compound analogous to hypochlorites found in common
bleaches, and in immune cells. In many ways, hypobromite functions in the same manner as
hypochlorite, and is also used as a germicide and antiparasitic in both industrial applications, and in the
immune system. For example, BrO can oxidize sulfhydryl groups in proteins. Which molecular orbital(s)
of BrO would you predict to interact most strongly with the sulfhydryl groups in the protein to oxidize
them? Explain.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F51435bf2-32bb-499c-aa57-a85dc35bd95d%2F038f1a0f-3cce-496a-a03b-2db1cc1f2af8%2Ffxfoymc_processed.jpeg&w=3840&q=75)
Transcribed Image Text:1) Prepare a molecular orbital energy-level diagram for BrO [sp mixing is not significant in BrO]
Orbital potential energies: Br: 4s -24.37 eV, 4p -12.49 eV; O: 2s -32.38 eV, 2p: -15.85 eV
2) Sketch the molecular orbital pictures (schematic representations) for the HOMO and LUMO in your
MO diagram.
3) Hypobromite (BrO) is the bromine compound analogous to hypochlorites found in common
bleaches, and in immune cells. In many ways, hypobromite functions in the same manner as
hypochlorite, and is also used as a germicide and antiparasitic in both industrial applications, and in the
immune system. For example, BrO can oxidize sulfhydryl groups in proteins. Which molecular orbital(s)
of BrO would you predict to interact most strongly with the sulfhydryl groups in the protein to oxidize
them? Explain.
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