Can you provide provide examples and mechanism and the rules?

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question

Can you provide provide examples and mechanism and the rules?

List of Reducing Agents:
(i) H2, Pd-C
(ii) 1. NaBH4 2.H3O+
alkyl halides.
Reduces C-C without effecting C=O
Reduces aldehydes to 1° alcohols and ketones to 2º alcohols;
does not reduce carboxylic acid, ester or C=C.
(iii) 1. LiAlH4 2. H+ ------ Reduces aldehydes, carboxylic acids and esters to 10 alcohl and
ketones to 2º alcohols. Does not reduce C-C.
(iv) BH3 or 9-BBN, THF (Stills Reduction)-----Reduces carboxylix acids to 1° alcohols.
REDUCTION
RC(O)H, RC(O)R, RCOOH, RCOOR
aldehyde, ketone, carboxylic acid, ester
From R-X
(alkyl ha
This is a selective reduction. Reduces only carboxylic acids
even in presence esters, nitriles, ketones etc.
Transcribed Image Text:List of Reducing Agents: (i) H2, Pd-C (ii) 1. NaBH4 2.H3O+ alkyl halides. Reduces C-C without effecting C=O Reduces aldehydes to 1° alcohols and ketones to 2º alcohols; does not reduce carboxylic acid, ester or C=C. (iii) 1. LiAlH4 2. H+ ------ Reduces aldehydes, carboxylic acids and esters to 10 alcohl and ketones to 2º alcohols. Does not reduce C-C. (iv) BH3 or 9-BBN, THF (Stills Reduction)-----Reduces carboxylix acids to 1° alcohols. REDUCTION RC(O)H, RC(O)R, RCOOH, RCOOR aldehyde, ketone, carboxylic acid, ester From R-X (alkyl ha This is a selective reduction. Reduces only carboxylic acids even in presence esters, nitriles, ketones etc.
Expert Solution
steps

Step by step

Solved in 5 steps with 4 images

Blurred answer
Knowledge Booster
Polymerization Kinetics
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY