Calculate AHrxn for the following reaction: 5C(s) + 6H2 (g) → C;H12 (1) Use the following reactions and given AH values: C5 H12(1) + 802 (g) → 5CO2(g) +6H2O(g), C(s) + O2 (g) → CO2(g), 2H2 (g) + O2 (g) → 2H2O(g), ΔΗ -3244.8 kJ ΔΗ -393.5 kJ ΔΗ -483.5 kJ Express your answer to four significant figures in kilojoules.
Basics in Organic Reactions Mechanisms
In organic chemistry, the mechanism of an organic reaction is defined as a complete step-by-step explanation of how a reaction of organic compounds happens. A completely detailed mechanism would relate the first structure of the reactants with the last structure of the products and would represent changes in structure and energy all through the reaction step.
Heterolytic Bond Breaking
Heterolytic bond breaking is also known as heterolysis or heterolytic fission or ionic fission. It is defined as breaking of a covalent bond between two different atoms in which one atom gains both of the shared pair of electrons. The atom that gains both electrons is more electronegative than the other atom in covalent bond. The energy needed for heterolytic fission is called as heterolytic bond dissociation energy.
Polar Aprotic Solvent
Solvents that are chemically polar in nature and are not capable of hydrogen bonding (implying that a hydrogen atom directly linked with an electronegative atom is not found) are referred to as polar aprotic solvents. Some commonly used polar aprotic solvents are acetone, DMF, acetonitrile, DMSO, etc.
Oxygen Nucleophiles
Oxygen being an electron rich species with a lone pair electron, can act as a good nucleophile. Typically, oxygen nucleophiles can be found in these compounds- water, hydroxides and alcohols.
Carbon Nucleophiles
We are aware that carbon belongs to group IV and hence does not possess any lone pair of electrons. Implying that neutral carbon is not a nucleophile then how is carbon going to be nucleophilic? The answer to this is that when a carbon atom is attached to a metal (can be seen in the case of organometallic compounds), the metal atom develops a partial positive charge and carbon develops a partial negative charge, hence making carbon nucleophilic.
![### Calculating the Enthalpy Change for a Chemical Reaction
#### Problem Statement
Calculate the \( \Delta H_{\text{rxn}} \) for the following reaction:
\[ 5C(s) + 6H_2(g) \rightarrow C_5H_{12}(l) \]
#### Given Data
Use the following reactions and their given \( \Delta H \) values:
1. \( C_5H_{12}(l) + 8O_2(g) \rightarrow 5CO_2(g) + 6H_2O(g) \)
- \( \Delta H = -3244.8 \, \text{kJ} \)
2. \( C(s) + O_2(g) \rightarrow CO_2(g) \)
- \( \Delta H = -393.5 \, \text{kJ} \)
3. \( 2H_2(g) + O_2(g) \rightarrow 2H_2O(g) \)
- \( \Delta H = -483.5 \, \text{kJ} \)
#### Task
Express your answer to four significant figures in kilojoules.
#### Explanation Method
To find the enthalpy change for the desired reaction, we can use Hess's Law. Hess's Law states that if a reaction is carried out in a series of steps, the \( \Delta H \) for the overall reaction is the sum of the \( \Delta H \) values for each individual step.
The given reactions and \( \Delta H \) values can be used to form the target reaction.
1. **Combustion of \( C_5H_{12} \)**:
\[ C_5H_{12}(l) + 8O_2(g) \rightarrow 5CO_2(g) + 6H_2O(g) \]
\[ \Delta H = -3244.8 \, \text{kJ} \]
2. **Formation of \( CO_2 \) from Carbon**:
\[ 5C(s) + 5O_2(g) \rightarrow 5CO_2(g) \]
\[ \Delta H = 5 \times (-393.5 \, \text{kJ}) = -1967.5 \, \text{kJ} \]
3. **Formation of](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ff89f5582-9fdc-4ede-82bb-28c01b8ca835%2F7562c854-901f-460b-8101-94e9df3085bc%2Ftfxfstg_processed.png&w=3840&q=75)
Step by step
Solved in 3 steps
