Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
Did I calculate the first atom economy correctly? Is H2SO4 the catalyst which would mean I would not include it in the denominator?
![### Understanding Atom Economy in Organic Synthesis
#### Reaction 1: Dehydration of 2-Methyl-2-butanol
**Equation:**
\[ \text{2-Methyl-2-butanol} \xrightarrow{\text{Heat, H}_2\text{SO}_4} \text{2-Methyl-1-butene} + \text{2-Methyl-2-butene} + \text{H}_2\text{O} \]
- **Molecular Weight of Reactants:**
- 2-Methyl-2-butanol: 88.15 g/mol
- **Molecular Weights of Products:**
- 2-Methyl-1-butene: 70.13 g/mol
**Atom Economy Calculation:**
\[
\text{Atom Economy} = \left(\frac{\text{Sum of Molecular Weight of Desired Products}}{\text{Sum of Molecular Weight of Reactants}}\right) \times 100
\]
\[
= \left(\frac{70.13 \, \text{g/mol}}{88.15 \, \text{g/mol}}\right) \times 100 = 79.5\%
\]
#### Reaction 2: Dehydrohalogenation of 2-Iodo-2-methylbutane
**Equation:**
\[ \text{2-Iodo-2-methylbutane} \xrightarrow{\text{Heat, KOtBu}} \text{2-Methyl-1-butene} + \text{2-Methyl-2-butene} \]
- **Molecular Weight of Reactant:**
- 2-Iodo-2-methylbutane: 198.05 g/mol
- **Molecular Weight of Additional Reagent:**
- KOtBu: 112.12 g/mol
- **Molecular Weight of Desired Product:**
- 2-Methyl-1-butene: 70.13 g/mol
**Atom Economy Calculation:**
\[
= \left(\frac{70.13 \, \text{g/mol}}{198.05 \, \text{g/mol} + 112.12 \, \text{g/mol}}\right) \times 100 = 22.6\%
\]
### Conclusion
The first reaction, dehydrating 2-Methyl-2-butanol, has a higher](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fb0d56cf4-ae0c-4387-a2fc-13a29f1b7e32%2F6ac7ea0f-872d-4394-9729-8186b536f54f%2F1rdfqb9_processed.jpeg&w=3840&q=75)
Transcribed Image Text:### Understanding Atom Economy in Organic Synthesis
#### Reaction 1: Dehydration of 2-Methyl-2-butanol
**Equation:**
\[ \text{2-Methyl-2-butanol} \xrightarrow{\text{Heat, H}_2\text{SO}_4} \text{2-Methyl-1-butene} + \text{2-Methyl-2-butene} + \text{H}_2\text{O} \]
- **Molecular Weight of Reactants:**
- 2-Methyl-2-butanol: 88.15 g/mol
- **Molecular Weights of Products:**
- 2-Methyl-1-butene: 70.13 g/mol
**Atom Economy Calculation:**
\[
\text{Atom Economy} = \left(\frac{\text{Sum of Molecular Weight of Desired Products}}{\text{Sum of Molecular Weight of Reactants}}\right) \times 100
\]
\[
= \left(\frac{70.13 \, \text{g/mol}}{88.15 \, \text{g/mol}}\right) \times 100 = 79.5\%
\]
#### Reaction 2: Dehydrohalogenation of 2-Iodo-2-methylbutane
**Equation:**
\[ \text{2-Iodo-2-methylbutane} \xrightarrow{\text{Heat, KOtBu}} \text{2-Methyl-1-butene} + \text{2-Methyl-2-butene} \]
- **Molecular Weight of Reactant:**
- 2-Iodo-2-methylbutane: 198.05 g/mol
- **Molecular Weight of Additional Reagent:**
- KOtBu: 112.12 g/mol
- **Molecular Weight of Desired Product:**
- 2-Methyl-1-butene: 70.13 g/mol
**Atom Economy Calculation:**
\[
= \left(\frac{70.13 \, \text{g/mol}}{198.05 \, \text{g/mol} + 112.12 \, \text{g/mol}}\right) \times 100 = 22.6\%
\]
### Conclusion
The first reaction, dehydrating 2-Methyl-2-butanol, has a higher
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
Step by step
Solved in 3 steps with 2 images
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY