Based on the spectra provided, draw the structure. Label each unique carbon and hydrogen with the letters A, B, C… for use in assigning NMR peaks. fill in the data table assigning peaks in each spectrum. You should assign: • All 1H NMR peaks (do not worry about the peaks for CDCl3 at 7.26 ppm or the peak for TMS at 0 ppm) • Significant IR peaks above 1600 cm
Based on the spectra provided, draw the structure. Label each unique carbon and hydrogen with the letters A, B, C… for use in assigning NMR peaks. fill in the data table assigning peaks in each spectrum. You should assign:
• All 1H NMR peaks (do not worry about the peaks for CDCl3 at 7.26 ppm or the peak for TMS at 0 ppm)
• Significant IR peaks above 1600 cm
Example of what the table should include (imagine the structure of ethanol is drawn with the CH3 hydrogens labeled as A, the CH2 hydrogens labeled as B, and the OH hydrogen labeled as C) :
hydrogen | proton chemical shift | integration | splitting pattern | couples to.. |
A | 1.2 | 3 | triplet | B |
B | 3.7 | 2 | quartet | A |
C | 2.6 | 1 | singlet | - |
![CDC13
240
12
220
11
200
10
QE-300
180
9
160
8
140
7
120
6
100
5
80
4
60
3
40
2
20
1
0](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ff57d3743-5e44-4060-83da-5d90a37d31c6%2F442f8f6e-b09b-47eb-be45-e65c53b9b716%2Fz2tmjx_processed.png&w=3840&q=75)
![The M+ peak is at 164 m/z.
100
Relative Intensity
LOD
TRANSMITTANCE!!
D
80-
60
40
20
4000
0
25
2990 49 1427 72
2952 36
2936 37
2912 46
2832 42
1464 84
1445 68
1102 13
9
1390 50 1079
1373 64
1283 79
1193 46
1181 49
1117 4
3000
1057 13
1003 72
993 74
984 77
972 72
50
|||||
938 70
908 55
892 62
876 72
855 81
589 79
584 81
2000
75
m/z
HAVENUMBERI-11
1500
mm
100
ww
1000
tr
125
500](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ff57d3743-5e44-4060-83da-5d90a37d31c6%2F442f8f6e-b09b-47eb-be45-e65c53b9b716%2F1005x25_processed.png&w=3840&q=75)
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In this Q, we have been given just the IR, NMR, and MS of the compound.
We can also see from the MS that the M+ peak is 164 - meaning the molar mass of this compound is 164.
At the onset, this set of data looks inadequate for a proper structure determination but one can still give this a try.
Let us look at the IR first.
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can you also include another table with ir data, where one column is wavenumber (cm^-1) and the other column is
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