2. a. Considering the five compounds shown below, which one matches the given ¹H NMR spectrum? Circle your answer. 5 2H D 3H 3 B 1H O illle ellle PPM O= E 6H b. Clearly match each peak in the NMR spectrum to a specific set of H atoms in your chosen structure. Use Ha, Hb, etc. for your labels on both your structure and the spectrum. c. List all of the compounds (A, B, C, D, E) that you would expect to have an IR peak at 1710 cm-¹? If none, write "NONE".
2. a. Considering the five compounds shown below, which one matches the given ¹H NMR spectrum? Circle your answer. 5 2H D 3H 3 B 1H O illle ellle PPM O= E 6H b. Clearly match each peak in the NMR spectrum to a specific set of H atoms in your chosen structure. Use Ha, Hb, etc. for your labels on both your structure and the spectrum. c. List all of the compounds (A, B, C, D, E) that you would expect to have an IR peak at 1710 cm-¹? If none, write "NONE".
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![## Question 2
### a. Considering the five compounds shown below, which one matches the given \( ^1H \) NMR spectrum? Circle your answer.
**Compounds:**
- **A:** ![Compound A](image_of_compound_A)
- **B:** ![Compound B](image_of_compound_B)
- **C:** ![Compound C](image_of_compound_C)
- **D:** ![Compound D](image_of_compound_D)
- **E:** ![Compound E](image_of_compound_E)
**NMR Spectrum Explanation:**
The provided \( ^1H \) NMR spectrum includes:
- A signal at approximately 3.8 ppm integrating to 2H.
- A signal at approximately 1.2 ppm integrating to 6H.
- A signal at approximately 1.1 ppm integrating to 3H.
- A signal at approximately 2.2 ppm integrating to 1H.
### b. Clearly match each peak in the NMR spectrum to a specific set of H atoms in your chosen structure. Use Ha, Hb, etc. for your labels on both your structure and spectrum.
In compound E, the peaks can be assigned as follows:
- The peak at 3.8 ppm (2H) corresponds to Ha.
- The peak at 1.2 ppm (6H) corresponds to Hb.
- The peak at 1.1 ppm (3H) corresponds to Hc.
- The peak at 2.2 ppm (1H) corresponds to Hd.
### c. List all of the compounds (A, B, C, D, E) that you would expect to have an IR peak at 1710 cm^-1. If none, write “NONE”.
The compounds expected to have a peak at 1710 cm^-1 are those containing a carbonyl group (C=O):
- **B**
- **C**
- **E**
### d. List all of the compounds (A, B, C, D, E) that you would expect to have an IR peak at 3300 cm^-1. If none, write “NONE”.
The IR peak at 3300 cm^-1 indicates an O-H (assuming alcohol or phenol) or N-H bond:
- **NONE**
### e. List all of the compounds (A, B, C, D, E) that you would expect to have an](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F797d4819-9880-4fca-9769-bf57521e6e40%2F2ade8241-4d25-4412-8acd-ade91ec4f2ec%2F7zqhrb5_processed.png&w=3840&q=75)
Transcribed Image Text:## Question 2
### a. Considering the five compounds shown below, which one matches the given \( ^1H \) NMR spectrum? Circle your answer.
**Compounds:**
- **A:** ![Compound A](image_of_compound_A)
- **B:** ![Compound B](image_of_compound_B)
- **C:** ![Compound C](image_of_compound_C)
- **D:** ![Compound D](image_of_compound_D)
- **E:** ![Compound E](image_of_compound_E)
**NMR Spectrum Explanation:**
The provided \( ^1H \) NMR spectrum includes:
- A signal at approximately 3.8 ppm integrating to 2H.
- A signal at approximately 1.2 ppm integrating to 6H.
- A signal at approximately 1.1 ppm integrating to 3H.
- A signal at approximately 2.2 ppm integrating to 1H.
### b. Clearly match each peak in the NMR spectrum to a specific set of H atoms in your chosen structure. Use Ha, Hb, etc. for your labels on both your structure and spectrum.
In compound E, the peaks can be assigned as follows:
- The peak at 3.8 ppm (2H) corresponds to Ha.
- The peak at 1.2 ppm (6H) corresponds to Hb.
- The peak at 1.1 ppm (3H) corresponds to Hc.
- The peak at 2.2 ppm (1H) corresponds to Hd.
### c. List all of the compounds (A, B, C, D, E) that you would expect to have an IR peak at 1710 cm^-1. If none, write “NONE”.
The compounds expected to have a peak at 1710 cm^-1 are those containing a carbonyl group (C=O):
- **B**
- **C**
- **E**
### d. List all of the compounds (A, B, C, D, E) that you would expect to have an IR peak at 3300 cm^-1. If none, write “NONE”.
The IR peak at 3300 cm^-1 indicates an O-H (assuming alcohol or phenol) or N-H bond:
- **NONE**
### e. List all of the compounds (A, B, C, D, E) that you would expect to have an
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